Adsorption and kinetic desorption study of Eu152+154(III) on multiwall carbon nanotubes from aqueous solution by using chelating resin and XPS methods
文献类型：期刊论文
| 作者 | Tan, X. L.1; Xu, D.1; Chen, C. L.1; Wang, X. K.1; Hu, W. P.2 |
| 刊名 | RADIOCHIMICA ACTA
 |
| 出版日期 | 2008 |
| 卷号 | 96期号:1页码:23-29 |
| 关键词 | Carbon Nanotubes Eu (Iii) Adsorption Xps Kinetic Desorption |
| ISSN号 | 0033-8230 |
| DOI | 10.1524/ract.2008.1457 |
| 英文摘要 | Multiwall carbon nanotubes (MWCNTs) have been pretreated with HNO3 and used for the adsorption of radionuclide Eu152+154(III) from aqueous solutions. The effects of pH (2-12), ionic strength (0.01 M and 0.1 M NaClO4) and radionuclide Eu152+154(III) solution concentrations (10(-8)-10(-5) mol/L) on the adsorption of Eu152+154(III) on MWCNTs were investigated. The experiments were carried out at 25 +/- 2 degrees C and under atmosphere conditions. Adsorption of Eu152+154(III) on MWCNTs increases significantly with increasing pH at pH < 6, and over 96% Eu152+154(III) are adsorbed on MWCNTs at pH > 6. Strong surface complexation and/or chemisorptions are considered as the main adsorption mechanism. The sorption was also characterized by using high resolution XPS spectra. The results show that MWCNTs can be a promising candidate of adsorbent for preconcentration of lanthanides from large volumes in radioactive nuclear waste management. |
| 语种 | 英语 |
| WOS记录号 | WOS:000252710100003 |
| 出版者 | OLDENBOURG VERLAG |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/63813]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Wang, X. K. |
| 作者单位 | 1.Chinese Acad Sci, Inst Plasma Phys, Hefei 230031, Anhui, Peoples R China 2.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Tan, X. L.,Xu, D.,Chen, C. L.,et al. Adsorption and kinetic desorption study of Eu152+154(III) on multiwall carbon nanotubes from aqueous solution by using chelating resin and XPS methods[J]. RADIOCHIMICA ACTA,2008,96(1):23-29. |
| APA | Tan, X. L.,Xu, D.,Chen, C. L.,Wang, X. K.,&Hu, W. P..(2008).Adsorption and kinetic desorption study of Eu152+154(III) on multiwall carbon nanotubes from aqueous solution by using chelating resin and XPS methods.RADIOCHIMICA ACTA,96(1),23-29. |
| MLA | Tan, X. L.,et al."Adsorption and kinetic desorption study of Eu152+154(III) on multiwall carbon nanotubes from aqueous solution by using chelating resin and XPS methods".RADIOCHIMICA ACTA 96.1(2008):23-29. |
入库方式： OAI收割
来源：化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。