Preparation of porous chromium oxide nanotubes using carbon nanotubes as templates and their application as an ethanol sensor
文献类型:期刊论文
作者 | An, Guimin1; Zhang, Yang2; Liu, Zhimin1; Miao, Zhenjiang1; Han, Buxing1; Miao, Shiding1; Li, Jianping2 |
刊名 | NANOTECHNOLOGY
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出版日期 | 2008-01-23 |
卷号 | 19期号:3 |
ISSN号 | 0957-4484 |
DOI | 10.1088/0957-4484/19/03/035504 |
英文摘要 | Chromium oxide nanotubes were successfully prepared using multi-walled carbon nanotubes (MWCNTs) as a template via a supercritical fluid-mediated route. In this method, with chromium (III) nitrate nonahydrate as precursor, chromium oxide was first deposited on MWCNTs in supercritical ethanol in the presence of NH(4)HCO(3). The as-prepared chromium oxide/MWCNT nanocomposites were characterized by transmission electron microscopy, x-ray diffraction, infrared spectroscopy and thermogravimetric analysis. It was demonstrated that the MWCNTs were coated with a layer of amorphous Cr(2)O(3)center dot xH(2)O. The thickness of the Cr(2)O(3)center dot xH(2)O sheath on MWCNTs could be tuned by manipulating the ratio of precursor to MWCNTs. Calcining the composites at 550 degrees C, the MWCNTs were removed, producing polycrystalline alpha-Cr(2)O(3) nanotubes. The as-prepared alpha-Cr(2)O(3) sample was used as a sensor material to detect ethanol vapor, and it was demonstrated that the alpha-Cr(2)O(3) nanotubes exhibited good performance even at 400 degrees C. |
语种 | 英语 |
WOS记录号 | WOS:000252967700012 |
出版者 | IOP PUBLISHING LTD |
源URL | [http://ir.iccas.ac.cn/handle/121111/63841] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Liu, Zhimin |
作者单位 | 1.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing Natl Lab Mol Sci BNLMS, Beijing 100080, Peoples R China 2.Chinese Acad Sci, Inst Elect, State Key Lab Transducer Technol, Beijing 100080, Peoples R China |
推荐引用方式 GB/T 7714 | An, Guimin,Zhang, Yang,Liu, Zhimin,et al. Preparation of porous chromium oxide nanotubes using carbon nanotubes as templates and their application as an ethanol sensor[J]. NANOTECHNOLOGY,2008,19(3). |
APA | An, Guimin.,Zhang, Yang.,Liu, Zhimin.,Miao, Zhenjiang.,Han, Buxing.,...&Li, Jianping.(2008).Preparation of porous chromium oxide nanotubes using carbon nanotubes as templates and their application as an ethanol sensor.NANOTECHNOLOGY,19(3). |
MLA | An, Guimin,et al."Preparation of porous chromium oxide nanotubes using carbon nanotubes as templates and their application as an ethanol sensor".NANOTECHNOLOGY 19.3(2008). |
入库方式: OAI收割
来源:化学研究所
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