2-(1-Isopropyl-2-benzimidazolyl)-6-(1-aryliminoethyl)pyridyl transition metal (Fe, Co, and Ni) dichlorides: Syntheses, characterizations and their catalytic behaviors toward ethylene reactivity
文献类型：期刊论文
| 作者 | Chen, Yanjun1,2; Hao, Peng1; Zuo, Weiwei1; Gao, Kun1,2; Sun, Wen-Hua1,2
|
| 刊名 | JOURNAL OF ORGANOMETALLIC CHEMISTRY
 |
| 出版日期 | 2008-05-01 |
| 卷号 | 693期号:10页码:1829-1840 |
| 关键词 | Transition Metal Complex Iron Cobalt Nickel 2-(Benzimidazolyl)-6-iminopyridine Ethylene Reactivity |
| ISSN号 | 0022-328X |
| DOI | 10.1016/j.jorganchem.2008.02.007 |
| 英文摘要 | A series of 2-(1-isopropyl-2- benzimidazolyl)-6-(1-aryliminoethyl) pyridyl metal complexes [iron (II) (1a-6a), cobalt (II) (1b-6b) and nickel (II) (1c-6c)] were synthesized and fully characterized by elemental and spectroscopic analyses. Single-crystal X-ray diffraction analyses of five coordinated complexes 5a, 3b, 5b, 1c and 2c reveal 5a and 5b as distorted trigonal-bipyramidal geometry, and 3b, 1c and 2c as distorted square pyramidal geometry. All complexes performed ethylene reactivity with the assistance of various organoaluminums. The iron complexes displayed good activities in the presence of MAO and MMAO. Upon activated by Et(2)AlCl, the cobalt analogues showed moderate ethylene reactivity, while the nickel analogues exhibited relatively higher activities. (C) 2008 Elsevier B.V. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000255891700013 |
| 出版者 | ELSEVIER SCIENCE SA |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/63849]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Gao, Kun |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Key Lab Engn Plast, Beijing Natl Lab Mol Sci, Beijing 100080, Peoples R China 2.Lanzhou Univ, Coll Chem & Chem Engn, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China |
| 推荐引用方式 GB/T 7714 | Chen, Yanjun,Hao, Peng,Zuo, Weiwei,et al. 2-(1-Isopropyl-2-benzimidazolyl)-6-(1-aryliminoethyl)pyridyl transition metal (Fe, Co, and Ni) dichlorides: Syntheses, characterizations and their catalytic behaviors toward ethylene reactivity[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY,2008,693(10):1829-1840. |
| APA | Chen, Yanjun,Hao, Peng,Zuo, Weiwei,Gao, Kun,&Sun, Wen-Hua.(2008).2-(1-Isopropyl-2-benzimidazolyl)-6-(1-aryliminoethyl)pyridyl transition metal (Fe, Co, and Ni) dichlorides: Syntheses, characterizations and their catalytic behaviors toward ethylene reactivity.JOURNAL OF ORGANOMETALLIC CHEMISTRY,693(10),1829-1840. |
| MLA | Chen, Yanjun,et al."2-(1-Isopropyl-2-benzimidazolyl)-6-(1-aryliminoethyl)pyridyl transition metal (Fe, Co, and Ni) dichlorides: Syntheses, characterizations and their catalytic behaviors toward ethylene reactivity".JOURNAL OF ORGANOMETALLIC CHEMISTRY 693.10(2008):1829-1840. |
入库方式： OAI收割
来源：化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。