Photophysical properties of heteroleptic iridium complexes containing carbazole-functionalized beta-diketonates
文献类型：期刊论文
| 作者 | Liu, Zhiwei; Nie, Daobo; Bian, Zuqiang; Chen, Fangfang; Lou, Bin; Bian, Jiang; Huang, Chunhui |
| 刊名 | CHEMPHYSCHEM
 |
| 出版日期 | 2008-03-14 |
| 卷号 | 9期号:4页码:634-640 |
| 关键词 | Electrochemistry Charge Transfer Density Functional Calculations Iridium Photochemistry |
| ISSN号 | 1439-4235 |
| DOI | 10.1002/cphc.200700648 |
| 英文摘要 | Twelve iridium complexes with general formula of Ir((CN)-N-Lambda)(2)(LX) [(CN)-N-Lambda represents the cyclometalated ligand, i.e. 2-(2,4-difluorophenyl) pyridine (dtppy), 2-phenylpyridine (ppy), dibenzo{f, h}quinoxaline (DBQ); LX stands for beta-diketonate, i.e. acetyl acetonate (acac), 1-(carbazol-9-yl)-5,5-dimethylhexane-2,4-diketonate (CBDK), 1-(carbazol-9-yl)-5,5,6,6,7,7,7-heptafluoroheptane-2,4-diketonate (CHFDK), 1-(N-ethyl-carbazol-3-yl)-4,4,5,5,6,6,6-heptafluorohexane-1,3-diketonate (ECHFDK)l are synthesized, characterized and their photophysical properties are systemically studied. In addition, crystals of Ir(DBQ)(2)(CHFDK) and Ir(DBQ)(2)(acac) are obtained and characterized by single crystal X-ray diffraction. The choice of these iridium complexes provides an opportunity for tracing the effect of the triplet energy level of ancillary ligands on the photophysical and electrochemical behaviors. Data show that if the triplet energy level of the beta-diketonate is higher than that of the Ir((CN)-N-Lambda)(2) fragment and there is no superposition on the state density map, strong (LC)-L-3 or (MLCT)-M-3-based phosphorescence can be obtained. Alternatively, if the state density map of the two parts are in superposition, the (LC)-L-3 or (MLCT)-M-3-based transition will be quenched at room temperature. Density functional theory calculations show that these complexes can be divided into two categories. The lowest excited state is mainly determined by (CN)-N-Lambda but not beta-diketonate when the difference between the triplet energy levels of the two parts is large. However when this difference is very small, the lowest excited state will be determined by both sides. This provides a satisfactory explanation for the experimental observations. |
| 语种 | 英语 |
| WOS记录号 | WOS:000254461300017 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/63867]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Bian, Zuqiang |
| 作者单位 | Beijing Univ, Coll Chem & Mol Engn, State Key Lab Rare Earth Mat, BNLMS, Beijing 100871, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Zhiwei,Nie, Daobo,Bian, Zuqiang,et al. Photophysical properties of heteroleptic iridium complexes containing carbazole-functionalized beta-diketonates[J]. CHEMPHYSCHEM,2008,9(4):634-640. |
| APA | Liu, Zhiwei.,Nie, Daobo.,Bian, Zuqiang.,Chen, Fangfang.,Lou, Bin.,...&Huang, Chunhui.(2008).Photophysical properties of heteroleptic iridium complexes containing carbazole-functionalized beta-diketonates.CHEMPHYSCHEM,9(4),634-640. |
| MLA | Liu, Zhiwei,et al."Photophysical properties of heteroleptic iridium complexes containing carbazole-functionalized beta-diketonates".CHEMPHYSCHEM 9.4(2008):634-640. |
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来源：化学研究所
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