An improved synthetic protocol and plausible mechanism in forming acetylpyridines from 2,6-dicarbethoxypyridine
文献类型：期刊论文
| 作者 | Asma, Maliha1,2,3; Adewuyi, Sheriff1,2; Kuang, Xiaofei1,2; Badshah, Amin3; Sun, Wen-Hua1,2
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| 刊名 | LETTERS IN ORGANIC CHEMISTRY
 |
| 出版日期 | 2008-06-01 |
| 卷号 | 5期号:4页码:296-299 |
| 关键词 | 2-carbethoxy-6-acetylpyridine Claisen Ester Condensation Anti-claisen Reaction 2 2 6-diacetylpyridine 6-dicarbethoxypyridine |
| ISSN号 | 1570-1786 |
| 英文摘要 | 2-Carbethoxy-6-acetylpyridine and 2,6-diacetylpyridine were transformed in good yields from the reaction of 2,6-dicarbethoxypyridine and EtOAc in the presence of sodium along with/without an equivalent of ethanol to sodium in toluene. The beta-keto esters, the intermediates in the transformation of beta-keto carboxylate into acetyl group, were isolated for understanding the plausible mechanism. |
| 语种 | 英语 |
| WOS记录号 | WOS:000256193400011 |
| 出版者 | BENTHAM SCIENCE PUBL LTD |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/63907]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Sun, Wen-Hua |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Key Lab Engn Plast, Beijing 100080, Peoples R China 2.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100080, Peoples R China 3.Quaid I Azam Univ, Dept Chem, Islamabad 45320, Pakistan |
| 推荐引用方式 GB/T 7714 | Asma, Maliha,Adewuyi, Sheriff,Kuang, Xiaofei,et al. An improved synthetic protocol and plausible mechanism in forming acetylpyridines from 2,6-dicarbethoxypyridine[J]. LETTERS IN ORGANIC CHEMISTRY,2008,5(4):296-299. |
| APA | Asma, Maliha,Adewuyi, Sheriff,Kuang, Xiaofei,Badshah, Amin,&Sun, Wen-Hua.(2008).An improved synthetic protocol and plausible mechanism in forming acetylpyridines from 2,6-dicarbethoxypyridine.LETTERS IN ORGANIC CHEMISTRY,5(4),296-299. |
| MLA | Asma, Maliha,et al."An improved synthetic protocol and plausible mechanism in forming acetylpyridines from 2,6-dicarbethoxypyridine".LETTERS IN ORGANIC CHEMISTRY 5.4(2008):296-299. |
入库方式： OAI收割
来源：化学研究所
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