Acetonitrile-vapor-induced color and luminescence changes in a cyclometalated heteroleptic iridium complex
文献类型：期刊论文
| 作者 | Liu, Zhiwei; Bian, Zuqiang; Bian, Jiang; Li, Zhendong; Nie, Daobo; Huang, Chunhui |
| 刊名 | INORGANIC CHEMISTRY
 |
| 出版日期 | 2008-09-15 |
| 卷号 | 47期号:18页码:8025-8030 |
| ISSN号 | 0020-1669 |
| DOI | 10.1021/ic702141h |
| 英文摘要 | An iridium complex Plr(qnx) (iridium(III) bis(2-phenylpyridinato-N C-2) (quinoxaline-2-carboxylate)) is reported for its unique and fast vapochromic and vapoluminescent behaviors. The emission of Plr(qnx) is governed by the whole crystal rather than the individual molecule. Plr(qnx) has been found to exist as both black and red forms in the solid state. The black form can be transformed into the red form upon its exposure to acetonitrile or propiononitrile vapor, whereas no response was observed when it was exposed to other volatile organic Compounds. To understand the vapochromic and vapoluminescent behaviors, we determined crystal structures of both forms by X-ray diffraction. In addition, we employed density functional theory in investigating weak intermolecular interactions, such as hydrogen bonding and pi-pi interactions in the two forms. |
| 语种 | 英语 |
| WOS记录号 | WOS:000259093700018 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/64003]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Bian, Zuqiang |
| 作者单位 | Peking Univ, Coll Chem & Mol Engn, State Key Lab Rare Earth Mat Chem & Applicat, BNLMS, Beijing 100871, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Zhiwei,Bian, Zuqiang,Bian, Jiang,et al. Acetonitrile-vapor-induced color and luminescence changes in a cyclometalated heteroleptic iridium complex[J]. INORGANIC CHEMISTRY,2008,47(18):8025-8030. |
| APA | Liu, Zhiwei,Bian, Zuqiang,Bian, Jiang,Li, Zhendong,Nie, Daobo,&Huang, Chunhui.(2008).Acetonitrile-vapor-induced color and luminescence changes in a cyclometalated heteroleptic iridium complex.INORGANIC CHEMISTRY,47(18),8025-8030. |
| MLA | Liu, Zhiwei,et al."Acetonitrile-vapor-induced color and luminescence changes in a cyclometalated heteroleptic iridium complex".INORGANIC CHEMISTRY 47.18(2008):8025-8030. |
入库方式： OAI收割
来源：化学研究所
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