Folding a conjugated chain: Oligo(o-phenyleneethynylene-alt-p-phenyleneethynylene)
文献类型:期刊论文
作者 | Zhu, Ningbo; Hu, Wei; Han, Shuliang; Wang, Oi; Zhao, Dahui1 |
刊名 | ORGANIC LETTERS
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出版日期 | 2008-10-02 |
卷号 | 10期号:19页码:4283-4286 |
ISSN号 | 1523-7060 |
DOI | 10.1021/ol801677s |
英文摘要 | An oligo(o-phenyleneethynylene-alt-p-phenyleneethynylene) was synthesized to create a conjugated molecule capable of adopting a helical secondary structure. A special feature of such a folded molecule is that the effective directions of energy/charge transport via covalent conjugation and through pi-pi stacking are converged to be along the helix axis. The transition from random conformations to the helix, driven by solvophobic and aromatic stacking interactions, was controlled by solvent properties. UV-vis and fluorescence spectroscopies gave supportive evidence for the folding process. |
语种 | 英语 |
WOS记录号 | WOS:000259557700033 |
出版者 | AMER CHEMICAL SOC |
源URL | [http://ir.iccas.ac.cn/handle/121111/64063] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Zhao, Dahui |
作者单位 | 1.Peking Univ, BNLMS, Dept Appl Chem, Beijing 100871, Peoples R China 2.Peking Univ, Coll Chem, Minist Educ, Key Lab Polymer Chem & Phys, Beijing 100871, Peoples R China |
推荐引用方式 GB/T 7714 | Zhu, Ningbo,Hu, Wei,Han, Shuliang,et al. Folding a conjugated chain: Oligo(o-phenyleneethynylene-alt-p-phenyleneethynylene)[J]. ORGANIC LETTERS,2008,10(19):4283-4286. |
APA | Zhu, Ningbo,Hu, Wei,Han, Shuliang,Wang, Oi,&Zhao, Dahui.(2008).Folding a conjugated chain: Oligo(o-phenyleneethynylene-alt-p-phenyleneethynylene).ORGANIC LETTERS,10(19),4283-4286. |
MLA | Zhu, Ningbo,et al."Folding a conjugated chain: Oligo(o-phenyleneethynylene-alt-p-phenyleneethynylene)".ORGANIC LETTERS 10.19(2008):4283-4286. |
入库方式: OAI收割
来源:化学研究所
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