SYNTHESIS AND CHARACTERIZATION OF CONDUCTIVE POLY(m-TOLUIDINE) HOLLOW MICROSPHERES
文献类型：期刊论文
| 作者 | He Haiyong1,2; Zhu Ying1; Li Xin1; Wang Qibao2; Wan Meixiang1; Jiang Lei1 |
| 刊名 | ACTA POLYMERICA SINICA
 |
| 出版日期 | 2008-12-20 |
| 期号 | 12页码:1181-1184 |
| 关键词 | Poly(M-toluidine) Ammonium Persulfate Hollow Microspheres Template-free Method Self-assembly |
| ISSN号 | 1000-3304 |
| 英文摘要 | Self-assembled hollow microspheres of conductive poly( m-toluidine) (PMT) were simply synthesized by a template-free method in the presence of ammonium peroxydisulfate (APS) without adding an acidic dopant. The average diameter and the average shell thickness of the PMT hollow microspheres were measured to be 2 mu m and 140 nm, respectively. Although without adding acids as the dopants, it has been demonstrated that the PMT hollow microspheres are identical to the conducting state of PMT due to proton (H(2)SO(4)) produced during the polymerization, which are conformed by FTIR, UV-Visible spectroscopy and room-temperature conductivity measured by the four-probe method, especially the pH value in reaction solution decreases with increasing the polymerization time. It was proposed that a spherical micelles composed of m-toluidine in aqueous solutions is served as a soft-template in forming the PMT hollow spheres via a self-assembly process. |
| 语种 | 英语 |
| WOS记录号 | WOS:000262112700010 |
| 出版者 | SCIENCE PRESS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/64135]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | He Haiyong |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Beijing 100190, Peoples R China 2.China Univ Min & Technol, Sch Chem & Environm Engn, Beijing 100083, Peoples R China |
| 推荐引用方式 GB/T 7714 | He Haiyong,Zhu Ying,Li Xin,et al. SYNTHESIS AND CHARACTERIZATION OF CONDUCTIVE POLY(m-TOLUIDINE) HOLLOW MICROSPHERES[J]. ACTA POLYMERICA SINICA,2008(12):1181-1184. |
| APA | He Haiyong,Zhu Ying,Li Xin,Wang Qibao,Wan Meixiang,&Jiang Lei.(2008).SYNTHESIS AND CHARACTERIZATION OF CONDUCTIVE POLY(m-TOLUIDINE) HOLLOW MICROSPHERES.ACTA POLYMERICA SINICA(12),1181-1184. |
| MLA | He Haiyong,et al."SYNTHESIS AND CHARACTERIZATION OF CONDUCTIVE POLY(m-TOLUIDINE) HOLLOW MICROSPHERES".ACTA POLYMERICA SINICA .12(2008):1181-1184. |
入库方式： OAI收割
来源：化学研究所
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