Molecular weight dependence of phase Behavior of PEO/P(EO-b-DMS) blends: Application of Sanchez-Lacombe lattice fluid theory
文献类型：期刊论文
| 作者 | Li, Hongfei1,2; Jiang, Shichun1; Sun, Zhaoyan1; An, Lijia1 |
| 刊名 | JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS
 |
| 出版日期 | 2008-03-01 |
| 卷号 | 46期号:5页码:452-459 |
| 关键词 | Block Polymers Blends Phase Behavior Poly(Ethylene Oxide) Poly(Ethylene Oxide-b-dimethylsiloxane) Sanchez-lacombe Lattice Fluid Theory |
| ISSN号 | 0887-6266 |
| DOI | 10.1002/polb.21376 |
| 英文摘要 | Molecular weight dependence of phase separation behavior of the Poly (ethylene oxide) (PEO)/Poly(ethylene oxide-block-dimethylsiloxane) (P(EO-b-DMS)) blends was investigated by both experimental and theoretical methods. The cloud point curves of PEO/P(EO-b-DMS) blends were obtained by turbidity method. Based on Sanchez-Lacombe lattice fluid theory (SLLFT), the adjustable parameter, epsilon*(12)/k (quantifying the interaction energy between different components), was evaluated by fitting the experimental data in phase diagrams. To calculate the spinodals, binodals, and the volume changes of mixing for these blends, three modified combining rules of the scaling parameters for the block copolymer were introduced. The calculated binodals with those modified combining rules show good agreement with the experimental data. Furthermore, the calculated volume changes during mixing decrease with increasing molecular weight of PEO, and the relationship between the volume changes and temperature is quite different for the mixtures with different molecular weight of PEO. (C) 2008 Wiley Periodicals, Inc. |
| 语种 | 英语 |
| WOS记录号 | WOS:000253737500003 |
| 出版者 | JOHN WILEY & SONS INC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/64165]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Jiang, Shichun |
| 作者单位 | 1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Hongfei,Jiang, Shichun,Sun, Zhaoyan,et al. Molecular weight dependence of phase Behavior of PEO/P(EO-b-DMS) blends: Application of Sanchez-Lacombe lattice fluid theory[J]. JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS,2008,46(5):452-459. |
| APA | Li, Hongfei,Jiang, Shichun,Sun, Zhaoyan,&An, Lijia.(2008).Molecular weight dependence of phase Behavior of PEO/P(EO-b-DMS) blends: Application of Sanchez-Lacombe lattice fluid theory.JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS,46(5),452-459. |
| MLA | Li, Hongfei,et al."Molecular weight dependence of phase Behavior of PEO/P(EO-b-DMS) blends: Application of Sanchez-Lacombe lattice fluid theory".JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS 46.5(2008):452-459. |
入库方式： OAI收割
来源：化学研究所
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