Synthesis, characterization and catalytic behaviors of neutral nickel complexes: Arylnickel N-alkyl-6-(1-(arylimino)ethyl)picolinamide
文献类型：期刊论文
| 作者 | Shen, Miao1,2; Hao, Peng1,2; Sun, Wen-Hua1,2
|
| 刊名 | JOURNAL OF ORGANOMETALLIC CHEMISTRY
 |
| 出版日期 | 2008-04-15 |
| 卷号 | 693期号:8-9页码:1683-1695 |
| 关键词 | N-alkyl-6-(1-(Arylimino)Ethyl)Picolinamide Neutral Nickel Complex Ethylene Oligomerization Kumada-corriu Reaction Polymerization Of Methyl Methacrylate |
| ISSN号 | 0022-328X |
| DOI | 10.1016/j.jorganchem.2008.01.004 |
| 英文摘要 | A series of novel neutral nickel complexes, aryl (phenyl or naphthyl) nickel N-alkyl-6-(1-(arylimino) ethyl) picolinamides, were synthesized and characterized by NMR and IR spectroscopy and elemental analysis. Single-crystal X-ray diffraction analyses of the complexes C2, C3 and C7 reveal distorted square-planar geometry along with the molecular structure of one free ligand L1. On activation with diethylaluminum chloride (Et(2)AlCl), the nickel complexes exhibited moderate catalytic activities for ethylene oligomerization, and the catalytic activity was up to 2.45 x 10(5) g mol(-1)(Ni) h(-1) in the presence of 1 equiv. PPh(3). Moreover, these complexes also exhibit moderate activities for Kumada-Corriu reaction and polymerization of methyl methacrylate. (C) 2008 Elsevier B.V. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000255891400036 |
| 出版者 | ELSEVIER SCIENCE SA |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/64271]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Sun, Wen-Hua |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Key Lab Engn Plast, Beijing 100080, Peoples R China 2.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Shen, Miao,Hao, Peng,Sun, Wen-Hua. Synthesis, characterization and catalytic behaviors of neutral nickel complexes: Arylnickel N-alkyl-6-(1-(arylimino)ethyl)picolinamide[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY,2008,693(8-9):1683-1695. |
| APA | Shen, Miao,Hao, Peng,&Sun, Wen-Hua.(2008).Synthesis, characterization and catalytic behaviors of neutral nickel complexes: Arylnickel N-alkyl-6-(1-(arylimino)ethyl)picolinamide.JOURNAL OF ORGANOMETALLIC CHEMISTRY,693(8-9),1683-1695. |
| MLA | Shen, Miao,et al."Synthesis, characterization and catalytic behaviors of neutral nickel complexes: Arylnickel N-alkyl-6-(1-(arylimino)ethyl)picolinamide".JOURNAL OF ORGANOMETALLIC CHEMISTRY 693.8-9(2008):1683-1695. |
入库方式： OAI收割
来源：化学研究所
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