Synthesis, characterization and properties of asymmetric methide anion based ionic liquids containing nitrile groups
文献类型：期刊论文
| 作者 | Zou Ting1; Lu Liang1; Liu Xiu-Li1; Zhang Zhan1; Wang Li-Bing1; Fu Xian-Lei1; Gao Guo-Hua1; Kou Yuan2; He Ming-Yuan1 |
| 刊名 | CHINESE JOURNAL OF CHEMISTRY
 |
| 出版日期 | 2008-08-01 |
| 卷号 | 26期号:8页码:1469-1480 |
| 关键词 | Ionic Liquid Methide Anion Nitrile Group Asymmetric Coupling Reaction |
| ISSN号 | 1001-604X |
| 英文摘要 | A series of asymmetric methide anion based ionic liquids containing nitrile groups have been synthesized for the first time Using the method of ion-exchange between sodium/potassium methide and various quaternary bromide/chloride salts of trimethylamine, triethylamine, tributylamine, N-methylpyrrolidine, And N-methylimidazole.. All of the functionalised ionic liquids were characterized by IR, (1)H, (13)C NMR, MS and elemental analysis. The decomposition temperature of the ionic liquids measured via TGA ranged from 219 to 339 degrees C. The functionalised ionic liquid, [Bmim][C(CN)(2)COCH(3)], was used as a ligand for Suzuki coupling reaction. The yields Of the Coupling reaction increased 10%-15% by the addition of the functionalised ionic liquid, [Bmim][C(CN)(2)COCH(3)]. |
| 语种 | 英语 |
| WOS记录号 | WOS:000258940100021 |
| 出版者 | WILEY-BLACKWELL |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/64341]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Gao Guo-Hua |
| 作者单位 | 1.E China Normal Univ, Shanghai Key Lab Green Chem & Chem Proc, Dept Chem, Shanghai 200062, Peoples R China 2.Peking Univ, State Key Lab Struct Chem Unstable & Stable Speci, Coll Chem & Mol Engn, Beijing 100871, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zou Ting,Lu Liang,Liu Xiu-Li,et al. Synthesis, characterization and properties of asymmetric methide anion based ionic liquids containing nitrile groups[J]. CHINESE JOURNAL OF CHEMISTRY,2008,26(8):1469-1480. |
| APA | Zou Ting.,Lu Liang.,Liu Xiu-Li.,Zhang Zhan.,Wang Li-Bing.,...&He Ming-Yuan.(2008).Synthesis, characterization and properties of asymmetric methide anion based ionic liquids containing nitrile groups.CHINESE JOURNAL OF CHEMISTRY,26(8),1469-1480. |
| MLA | Zou Ting,et al."Synthesis, characterization and properties of asymmetric methide anion based ionic liquids containing nitrile groups".CHINESE JOURNAL OF CHEMISTRY 26.8(2008):1469-1480. |
入库方式： OAI收割
来源：化学研究所
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