Confinement effect on the body-centered-cubic phase of diblock copolymers in film
文献类型:期刊论文
作者 | Tan, Hongge1; Song, Qinggong1; Yang, Shuang2; Yan, Dadong2; Shi, An-Chang3 |
刊名 | MACROMOLECULAR THEORY AND SIMULATIONS
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出版日期 | 2008-01-24 |
卷号 | 17期号:1页码:45-51 |
关键词 | Block Copolymers Film Mean Field Surfaces Theory |
ISSN号 | 1022-1344 |
DOI | 10.1002/mats.200700064 |
英文摘要 | In this paper, we study the morphology of diblock copolymers with the body-centered-cubic (bcc) phase confined between two flat surfaces. Employing the Landau-Brazovskii mean field theory and the single mode approximation, we obtain three amplitude parameters as functions of temperature, surface field strength, and film thickness. Because of the effect of confinement size and the surface inducement, the morphology of confined diblock copolymers is different from the bulk structure. By controlling confinement size and surface field strength, lamella, undulated lamella, cylinder, and distorted cylinder can be observed in the bcc bulk phase of diblock copolymers. Also, we construct a "phase diagram" of confinement-induced structures at different surface field strengths. We compare the present theoretical results with the other relevant theoretical results. The predictions about these interesting confinement-induced structures should be observable in the experiments under suitable conditions. |
语种 | 英语 |
WOS记录号 | WOS:000252870200006 |
出版者 | WILEY-V C H VERLAG GMBH |
源URL | [http://ir.iccas.ac.cn/handle/121111/64355] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Tan, Hongge |
作者单位 | 1.Civil Aviat Univ China, Coll Sci, Tianjin 300300, Peoples R China 2.Chinese Acad Sci, Inst Chem, State Key Lab Polymer Phys & Chem, Beijing 100080, Peoples R China 3.McMaster Univ, Dept Phys & Astron, Hamilton, ON L8S 4M1, Canada |
推荐引用方式 GB/T 7714 | Tan, Hongge,Song, Qinggong,Yang, Shuang,et al. Confinement effect on the body-centered-cubic phase of diblock copolymers in film[J]. MACROMOLECULAR THEORY AND SIMULATIONS,2008,17(1):45-51. |
APA | Tan, Hongge,Song, Qinggong,Yang, Shuang,Yan, Dadong,&Shi, An-Chang.(2008).Confinement effect on the body-centered-cubic phase of diblock copolymers in film.MACROMOLECULAR THEORY AND SIMULATIONS,17(1),45-51. |
MLA | Tan, Hongge,et al."Confinement effect on the body-centered-cubic phase of diblock copolymers in film".MACROMOLECULAR THEORY AND SIMULATIONS 17.1(2008):45-51. |
入库方式: OAI收割
来源:化学研究所
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