中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Confinement effect on the body-centered-cubic phase of diblock copolymers in film

文献类型:期刊论文

作者Tan, Hongge1; Song, Qinggong1; Yang, Shuang2; Yan, Dadong2; Shi, An-Chang3
刊名MACROMOLECULAR THEORY AND SIMULATIONS
出版日期2008-01-24
卷号17期号:1页码:45-51
关键词Block Copolymers Film Mean Field Surfaces Theory
ISSN号1022-1344
DOI10.1002/mats.200700064
英文摘要In this paper, we study the morphology of diblock copolymers with the body-centered-cubic (bcc) phase confined between two flat surfaces. Employing the Landau-Brazovskii mean field theory and the single mode approximation, we obtain three amplitude parameters as functions of temperature, surface field strength, and film thickness. Because of the effect of confinement size and the surface inducement, the morphology of confined diblock copolymers is different from the bulk structure. By controlling confinement size and surface field strength, lamella, undulated lamella, cylinder, and distorted cylinder can be observed in the bcc bulk phase of diblock copolymers. Also, we construct a "phase diagram" of confinement-induced structures at different surface field strengths. We compare the present theoretical results with the other relevant theoretical results. The predictions about these interesting confinement-induced structures should be observable in the experiments under suitable conditions.
语种英语
WOS记录号WOS:000252870200006
出版者WILEY-V C H VERLAG GMBH
源URL[http://ir.iccas.ac.cn/handle/121111/64355]  
专题中国科学院化学研究所
通讯作者Tan, Hongge
作者单位1.Civil Aviat Univ China, Coll Sci, Tianjin 300300, Peoples R China
2.Chinese Acad Sci, Inst Chem, State Key Lab Polymer Phys & Chem, Beijing 100080, Peoples R China
3.McMaster Univ, Dept Phys & Astron, Hamilton, ON L8S 4M1, Canada
推荐引用方式
GB/T 7714
Tan, Hongge,Song, Qinggong,Yang, Shuang,et al. Confinement effect on the body-centered-cubic phase of diblock copolymers in film[J]. MACROMOLECULAR THEORY AND SIMULATIONS,2008,17(1):45-51.
APA Tan, Hongge,Song, Qinggong,Yang, Shuang,Yan, Dadong,&Shi, An-Chang.(2008).Confinement effect on the body-centered-cubic phase of diblock copolymers in film.MACROMOLECULAR THEORY AND SIMULATIONS,17(1),45-51.
MLA Tan, Hongge,et al."Confinement effect on the body-centered-cubic phase of diblock copolymers in film".MACROMOLECULAR THEORY AND SIMULATIONS 17.1(2008):45-51.

入库方式: OAI收割

来源:化学研究所

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