Curing behavior study of polydimethylsiloxane-modified allylated novolac/4,4 '-bismaleimidodiphenylmethane resin
文献类型:期刊论文
作者 | Li, Wanwan; Liu, Feng; Wei, Liuhe; Zhao, Tong |
刊名 | JOURNAL OF APPLIED POLYMER SCIENCE
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出版日期 | 2008-01-05 |
卷号 | 107期号:1页码:554-561 |
关键词 | Allylated Novolac Resin Polysiloxane Kinetics (Polym.) Infrared Spectroscopy Differential Scanning Calorimetry (Dsc) |
ISSN号 | 0021-8995 |
DOI | 10.1002/app.26300 |
英文摘要 | The curing behavior of polydimethylsiloxane-modified allylated. novolac/4,4'-bismaleimidodiphenylmethane resin (PDMS-modified AN/BDM) was investigated by using Fourier transform infrared spectrometry (FTIR) and differential scanning calorimetry. The results of FUR confirmed that the curing reactions of the PDMS-modified AN/BDM resins, including "Ene" reaction and Diels-Alder reaction between allyl groups and maleimide groups, should be similar to those of the parent allylated novolac/4,4'-bismaleimidodiphenytmethane (AN/BDM) resin. The results of dynamic DSC showed that the total curing enthalpy of the PDMS-modified AN/BDM resins was lower than that of the parent resin. Incorporation of polydimethylsiloxane (PDMS) into the backbone of the allylated novolac (AN) resin favored the Claisen rearrangement reaction of allyl groups. The isothermal DSC method was used to study the kinetics of the curing process. The experimental data for the parent AN/BDM resin and the PDMS-modified AN/BDM resins exhibited an nth-order behavior. (C) 2007 Wiley Periodicals, Inc. |
语种 | 英语 |
WOS记录号 | WOS:000250822200070 |
出版者 | JOHN WILEY & SONS INC |
源URL | [http://ir.iccas.ac.cn/handle/121111/64479] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Zhao, Tong |
作者单位 | 1.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
推荐引用方式 GB/T 7714 | Li, Wanwan,Liu, Feng,Wei, Liuhe,et al. Curing behavior study of polydimethylsiloxane-modified allylated novolac/4,4 '-bismaleimidodiphenylmethane resin[J]. JOURNAL OF APPLIED POLYMER SCIENCE,2008,107(1):554-561. |
APA | Li, Wanwan,Liu, Feng,Wei, Liuhe,&Zhao, Tong.(2008).Curing behavior study of polydimethylsiloxane-modified allylated novolac/4,4 '-bismaleimidodiphenylmethane resin.JOURNAL OF APPLIED POLYMER SCIENCE,107(1),554-561. |
MLA | Li, Wanwan,et al."Curing behavior study of polydimethylsiloxane-modified allylated novolac/4,4 '-bismaleimidodiphenylmethane resin".JOURNAL OF APPLIED POLYMER SCIENCE 107.1(2008):554-561. |
入库方式: OAI收割
来源:化学研究所
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