Optical properties of porphyrin chromophores assembled in nano-lamellar zirconium phosphate
文献类型：期刊论文
| 作者 | Shi, Shikao1,2; Zhou, Ji2; Han, Shitian1; Peng, Yanli1; Yea, Jianping3 |
| 刊名 | JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY
 |
| 出版日期 | 2008-03-01 |
| 卷号 | 8期号:3页码:1359-1363 |
| 关键词 | Assembly Luminescence Porphyrins Zirconium Phosphate Intercalation |
| ISSN号 | 1533-4880 |
| DOI | 10.1166/jnn.2008.331 |
| 英文摘要 | The supra-molecular assemblies and optical properties of the symmetrical neutral porphyrin chromophore, meso-tetra(4-pyridyl)porphine, bound to a modified a-zirconium phosphate framework have been studied. The interlayer distance of the cetyltrimethylammonium zirconium phosphate framework is 39.6 angstrom. After the addition of meso-tetra(4-pyridyl)porphine to the framework, the X-ray powder diffraction (XRPD) patterns show that the interlayer distance of the framework is 30.3 angstrom, demonstrating the formation of novel assemblies. In the framework, organic chromophores are assumed to align in a canted monolayer. The interaction of organic chromophores with the framework causes noticeable red shifts of the Soret absorption band from 416 to 427 nm. In contrast, the luminescence peak is blue shifted from 660 nm in aqueous media to 648 nm when mesotetra(4-pyridyl)porphine is bound to the framework. Furthermore, the emission yield of the organic chromophore in the framework is dramatically enhanced compared to that of organic aqueous solutions. The spectroscopic change of meso-tetra(4-pyridyl)porphine is ascribed to the unique microenvironments of the nano-lamellar framework. The juxtaposition of the porphyrin chromophores in the framework tunes their electronic interactions. In comparison, the organic chromophores also attempted to bind with another modified alpha-zirconium phosphate, n-butylammonium zirconium phosphate. However, the chromophores could not enter into n-butylammonium zirconium phosphate due to its smaller interlayer distance (18.8 angstrom). |
| 语种 | 英语 |
| WOS记录号 | WOS:000254540700050 |
| 出版者 | AMER SCIENTIFIC PUBLISHERS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/64599]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Shi, Shikao |
| 作者单位 | 1.Hebei Normal Univ, Coll Chem & Mat Sci, Shijiazhuang 050016, Peoples R China 2.Tsinghua Univ, Dept Mat Sci & Engn, Beijing 100084, Peoples R China 3.CAS, Inst Chem, Key Lab Photochem, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Shi, Shikao,Zhou, Ji,Han, Shitian,et al. Optical properties of porphyrin chromophores assembled in nano-lamellar zirconium phosphate[J]. JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY,2008,8(3):1359-1363. |
| APA | Shi, Shikao,Zhou, Ji,Han, Shitian,Peng, Yanli,&Yea, Jianping.(2008).Optical properties of porphyrin chromophores assembled in nano-lamellar zirconium phosphate.JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY,8(3),1359-1363. |
| MLA | Shi, Shikao,et al."Optical properties of porphyrin chromophores assembled in nano-lamellar zirconium phosphate".JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY 8.3(2008):1359-1363. |
入库方式： OAI收割
来源：化学研究所
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