Novel acid-base polyimides synthesized from binaphthalene dianhydrie and triphenylamine-containing diamine as proton exchange membranes
文献类型：期刊论文
| 作者 | Zhang, Feng1,2; Li, Nanwen1,2; Cui, Zhiming1,3; Zhang, Suobo1; Li, Shenghai1 |
| 刊名 | JOURNAL OF MEMBRANE SCIENCE
 |
| 出版日期 | 2008-04-30 |
| 卷号 | 314期号:1-2页码:24-32 |
| 关键词 | Sulfonated Polyimides Basic Triphenylamine Swelling Capacity Proton Conductivity Proton Exchange Membrane |
| ISSN号 | 0376-7388 |
| DOI | 10.1016/j.memsei.2008.01.032 |
| 英文摘要 | The synthesis and characterization of novel acid-base polyimide membranes for the use in polymer electrolyte membrane fuel cell is presented in this paper. The sulfonated polyimides (SPIs) bearing basic triphenylamine groups were easily synthesized using 4,4'-binaphthyl-1,1',8,8'-tetracarboxylic dianhydride (BTDA), sulfonated diamine of 4,4'-diaminodiphenyl ether-2,2'-disulfonic acid (ODADS), and nonsulfonated diamines of 4,4'-diaminotriphenylamine (DATPA). The effects of the structure of the dianhydride and diamines on the properties of SPI membranes were evaluated through the study of membrane parameters including water sorption, proton conductivity, water stability, dimensional changes, and methanol permeability. It was found that the BTDA-based sulfonated polyimides displayed much better hydrolytic stability than 1,4,5,8-naphthalenecarboxylic dianhydride (NTDA)-based polyimides. This is because the former has a decreased positive charge density in the imido rings compared to the latter ones. Furthermore, the present SPI membranes also displayed much better resistance to swelling than these without DATPA due to the strong interchain interaction through basic triphenylamine functions and sulfonic acid groups. The SPI membrane with IEC value of 2.21 mequiv./g shows the proton conductivity of 0.11 S/cm at 20 degrees C which is higher than Nation 117 (0.09 S/cm at 20 degrees C). Moreover, the SPI membranes exhibited excellent mechanical properties and decreased methanol permeability. (C) 2008 Elsevier B.V. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000255994600004 |
| 出版者 | ELSEVIER SCIENCE BV |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/64653]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Zhang, Suobo |
| 作者单位 | 1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China 3.State Key Lab Electroanalyt chem, Changchun 130022, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Feng,Li, Nanwen,Cui, Zhiming,et al. Novel acid-base polyimides synthesized from binaphthalene dianhydrie and triphenylamine-containing diamine as proton exchange membranes[J]. JOURNAL OF MEMBRANE SCIENCE,2008,314(1-2):24-32. |
| APA | Zhang, Feng,Li, Nanwen,Cui, Zhiming,Zhang, Suobo,&Li, Shenghai.(2008).Novel acid-base polyimides synthesized from binaphthalene dianhydrie and triphenylamine-containing diamine as proton exchange membranes.JOURNAL OF MEMBRANE SCIENCE,314(1-2),24-32. |
| MLA | Zhang, Feng,et al."Novel acid-base polyimides synthesized from binaphthalene dianhydrie and triphenylamine-containing diamine as proton exchange membranes".JOURNAL OF MEMBRANE SCIENCE 314.1-2(2008):24-32. |
入库方式： OAI收割
来源：化学研究所
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