Synthesis and characterization of novel fluorinated polyimides derived from 1,1 '-bis(4-aminophenyl)-1-(3-trifluoromethylphenyl)-2,2,2-trifluoroethane and aromatic dianhydrides
文献类型：期刊论文
| 作者 | Ge, Ziyi; Fan, Lin; Yang, Shiyong |
| 刊名 | EUROPEAN POLYMER JOURNAL
 |
| 出版日期 | 2008-04-01 |
| 卷号 | 44期号:4页码:1252-1260 |
| 关键词 | Fluorinated Polyimides Solubility Thermal Stability Dielectric Properties |
| ISSN号 | 0014-3057 |
| DOI | 10.1016/j.eurpolymj.2008.01.041 |
| 英文摘要 | A novel fluorinated aromatic diamine 1,1'-bis(4-aminophenyl)-1-(3-trifluoromethylphenyl)-2,2,2-trifluoroethane (6FDAM) was synthesized in a simple procedure, which was then employed to prepare a series of fluorinated polyimides with commercial aromatic dianhydrides, such as pyromellitic dianhydride (PMDA), 2,2-bis(3,4-dicarboxyphenyl)hexafluoropropane (6FDA), 3,3',4,4'-benzophenonetetracarboxylic dianhydride (BTDA) and 4,4'-oxydiphthalic anhydride (ODPA). The polyimides exhibited good solubility in strong dipolar solvents such as NMP, DMAc, DMF and in-cresol as well as some of low boiling point organic solvents of THF and CHCl3, etc. Experimental results indicated the polyimides possessed low moisture adsorptions of 0.42-0.95%, low dielectric constant of 2.71-2.95 at 1 MHz, high dielectric strength of 92.0-122.6 kV/mm and good optical transparency with cutoff wavelengths of UV-vis at 330-375 nm. The polyimides also exhibited good mechanical properties as well as excellent thermal and thermo-oxidative stability. The fluorinated polyimides possessed better solubility, lower dielectric constant and water adsorption as well as higher optical transparency than the representative non-fluorinated polyimide derived from PMDA and 4,4'-oxydianiline (ODA). (c) 2008 Elsevier Ltd. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000255625600032 |
| 出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/64655]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Ge, Ziyi |
| 作者单位 | Chinese Acad Sci, Inst Chem, Lab Adv Polymer Mat, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Ge, Ziyi,Fan, Lin,Yang, Shiyong. Synthesis and characterization of novel fluorinated polyimides derived from 1,1 '-bis(4-aminophenyl)-1-(3-trifluoromethylphenyl)-2,2,2-trifluoroethane and aromatic dianhydrides[J]. EUROPEAN POLYMER JOURNAL,2008,44(4):1252-1260. |
| APA | Ge, Ziyi,Fan, Lin,&Yang, Shiyong.(2008).Synthesis and characterization of novel fluorinated polyimides derived from 1,1 '-bis(4-aminophenyl)-1-(3-trifluoromethylphenyl)-2,2,2-trifluoroethane and aromatic dianhydrides.EUROPEAN POLYMER JOURNAL,44(4),1252-1260. |
| MLA | Ge, Ziyi,et al."Synthesis and characterization of novel fluorinated polyimides derived from 1,1 '-bis(4-aminophenyl)-1-(3-trifluoromethylphenyl)-2,2,2-trifluoroethane and aromatic dianhydrides".EUROPEAN POLYMER JOURNAL 44.4(2008):1252-1260. |
入库方式： OAI收割
来源：化学研究所
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