Aggregation and supramolecular chirality of achiral amphiphilic metalloporphyrins
文献类型：期刊论文
| 作者 | Yu, Wei1,2; Li, Zhanshuang2; Wang, Tianyu1; Liu, Minghua1 |
| 刊名 | JOURNAL OF COLLOID AND INTERFACE SCIENCE
 |
| 出版日期 | 2008-10-15 |
| 卷号 | 326期号:2页码:460-464 |
| 关键词 | Lb Film Supramolecular Chirality Aggregation Metalloporphyrin |
| ISSN号 | 0021-9797 |
| DOI | 10.1016/j.jcis.2008.06.049 |
| 英文摘要 | Metalloporphyrin derivatives with three hydrophobic dodecyl chains and a hydrophilic ester or carboxylic acid substituent were designed in order to clarify the effect of the central metal ions on the aggregation as well as the supramolecular chirality in the Langmuir-Schaefer films. All the metalloporphyrins showed good spreading behavior on water surface and can be transferred onto solid substrates. The transferred films were characterized by a variety of methods including UV-visible spectroscopy, circular dichroism (CID) spectroscopy, FTIR spectroscopy, atomic force microscopy (AFM) and scanning electron microscope (SEM) measurements. It has been found that the copper derivative forms J-aggregates as well as H-aggregates in the film. Moreover, the film showed strong CD signals. Change from the ester substitution to carboxylic acid caused the decrease of the supramolecular chirality. On the contrary, the zinc derivative showed only a negligible CD signal although the corresponding free base could assemble into a chiral assembly. A possible mechanism for the subtle relationship between supramolecular chirality and molecular structures has been proposed. (c) 2008 Elsevier Inc. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000259243600023 |
| 出版者 | ACADEMIC PRESS INC ELSEVIER SCIENCE |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/64743]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Wang, Tianyu |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100080, Peoples R China 2.Harbin Engn Univ, Sch Mat Sci & Chem Engn, Harbin 150001, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yu, Wei,Li, Zhanshuang,Wang, Tianyu,et al. Aggregation and supramolecular chirality of achiral amphiphilic metalloporphyrins[J]. JOURNAL OF COLLOID AND INTERFACE SCIENCE,2008,326(2):460-464. |
| APA | Yu, Wei,Li, Zhanshuang,Wang, Tianyu,&Liu, Minghua.(2008).Aggregation and supramolecular chirality of achiral amphiphilic metalloporphyrins.JOURNAL OF COLLOID AND INTERFACE SCIENCE,326(2),460-464. |
| MLA | Yu, Wei,et al."Aggregation and supramolecular chirality of achiral amphiphilic metalloporphyrins".JOURNAL OF COLLOID AND INTERFACE SCIENCE 326.2(2008):460-464. |
入库方式： OAI收割
来源：化学研究所
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