Orthogonal sample design scheme for two-dimensional synchronous spectroscopy: Application in probing lanthanide ions interactions with organic ligands in solution mixtures
文献类型：期刊论文
| 作者 | Qi, Jian1; Huang, Kun1; Gao, Xiuxiang1; Li, Huizhen1,4; Liu, Shaoxuan1; Zhao, Ying2; Xu, Yizhuang1; Wu, Jinguang1; Noda, Isao3 |
| 刊名 | JOURNAL OF MOLECULAR STRUCTURE
 |
| 出版日期 | 2008-07-30 |
| 卷号 | 883页码:116-123 |
| 关键词 | Orthogonal Sample Design Scheme 2d Correlation Analysis Synchronous Spectrum Cross Peaks Intermolecular Interaction |
| ISSN号 | 0022-2860 |
| DOI | 10.1016/j.molstruc.2008.01.036 |
| 英文摘要 | Weak interactions between lanthanide (III) ions and organic ligands in solution mixtures are studied by using two-dimensional synchronous spectroscopy together with "Orthogonal Sample Design" (OSD) scheme that can effectively remove the interfering cross peaks in 2D synchronous spectrum. Two representative chemical systems are investigated and discussed here: (1) PrCl(3)/butanone in ethanol solution, where weak coordinative interaction between Pr(3+) and carbonyl group from butanone is characterized by using 2D UV/IR heterogeneous spectroscopy; and (2) NdCl(3)/5-sulfosalicylic acid in aqueous solution, where the interaction between Nd(3+)/5-sulfosalicylic acid is investigated by using 2D UV spectra. The cross peaks occurred in the 2D spectra confirm the weak interactions between lanthanide (111) ions and corresponding molecules where no observable variation occurs in conventional I D spectra. (C) 2008 Elsevier B.V. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000257603000017 |
| 出版者 | ELSEVIER SCIENCE BV |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/64779]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Xu, Yizhuang |
| 作者单位 | 1.Peking Univ, Coll Chem & Mol Engn, Beijing 100871, Peoples R China 2.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China 3.Procter & Gamble Co, W Chester, OH 45069 USA 4.Henan Normal Univ, Coll Chem & Environm Sci, Xinxiang 453007, Peoples R China |
| 推荐引用方式 GB/T 7714 | Qi, Jian,Huang, Kun,Gao, Xiuxiang,et al. Orthogonal sample design scheme for two-dimensional synchronous spectroscopy: Application in probing lanthanide ions interactions with organic ligands in solution mixtures[J]. JOURNAL OF MOLECULAR STRUCTURE,2008,883:116-123. |
| APA | Qi, Jian.,Huang, Kun.,Gao, Xiuxiang.,Li, Huizhen.,Liu, Shaoxuan.,...&Noda, Isao.(2008).Orthogonal sample design scheme for two-dimensional synchronous spectroscopy: Application in probing lanthanide ions interactions with organic ligands in solution mixtures.JOURNAL OF MOLECULAR STRUCTURE,883,116-123. |
| MLA | Qi, Jian,et al."Orthogonal sample design scheme for two-dimensional synchronous spectroscopy: Application in probing lanthanide ions interactions with organic ligands in solution mixtures".JOURNAL OF MOLECULAR STRUCTURE 883(2008):116-123. |
入库方式： OAI收割
来源：化学研究所
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