Near-Infrared Electrochromic and Chiroptical Switching Materials: Design, Synthesis, and Characterization of Chiral Organogels Containing Stacked Naphthalene Diimide Chromophores
文献类型：期刊论文
| 作者 | Zheng, Jia1; Qiao, Wenqiang1; Wan, Xinhua1; Gao, Jian Ping2; Wang, Zhi Yuan2 |
| 刊名 | CHEMISTRY OF MATERIALS
 |
| 出版日期 | 2008-10-14 |
| 卷号 | 20期号:19页码:6163-6168 |
| ISSN号 | 0897-4756 |
| DOI | 10.1021/cm8014644 |
| 英文摘要 | Chiroptical switching materials in the visible and near-infrared spectral regions have been realized using a low molecular weight gel as a chiral scaffold and electrochromic chromophores as a stimulus-responsive trigger and operate as a result of the change in the electronic states of the chromophores within the chiral gel. N,N'-Bis(4-phenyl-2.3,4,6-tetra-O-acetyl-beta-D-glucopyranoside)-1,4,5,8-naphthale- netetracarboxylic diiinicle, synthesized by irniclization of 1.4,5,8-ii iphilialciieteti- tc irboxylic dianhydride with a sugar-bearing amine, call form stable chiral gels at room temperature. The redox-active gels exhibited reversible and drastic changes in circular dichroism in the visible and near-infrared spectral region between the three redox states (neutral, radical anion, dianion) of the naphthalene diimide chromophore. A large circular dichroism at 1310-1550 nm was induced when the stacked naphthalene diimide chromophores in the chiral gels were reduced to the radical anion state. |
| 语种 | 英语 |
| WOS记录号 | WOS:000259871500030 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/64833]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Wan, Xinhua |
| 作者单位 | 1.Peking Univ, Beijing Natl Lab Mol Sci, Key Lab Polymer Chem & Phys Minist Educ, Coll Chem & Mol Engn, Beijing 100871, Peoples R China 2.Carleton Univ, Dept Chem, Ottawa, ON K1S 5B6, Canada |
| 推荐引用方式 GB/T 7714 | Zheng, Jia,Qiao, Wenqiang,Wan, Xinhua,et al. Near-Infrared Electrochromic and Chiroptical Switching Materials: Design, Synthesis, and Characterization of Chiral Organogels Containing Stacked Naphthalene Diimide Chromophores[J]. CHEMISTRY OF MATERIALS,2008,20(19):6163-6168. |
| APA | Zheng, Jia,Qiao, Wenqiang,Wan, Xinhua,Gao, Jian Ping,&Wang, Zhi Yuan.(2008).Near-Infrared Electrochromic and Chiroptical Switching Materials: Design, Synthesis, and Characterization of Chiral Organogels Containing Stacked Naphthalene Diimide Chromophores.CHEMISTRY OF MATERIALS,20(19),6163-6168. |
| MLA | Zheng, Jia,et al."Near-Infrared Electrochromic and Chiroptical Switching Materials: Design, Synthesis, and Characterization of Chiral Organogels Containing Stacked Naphthalene Diimide Chromophores".CHEMISTRY OF MATERIALS 20.19(2008):6163-6168. |
入库方式： OAI收割
来源：化学研究所
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