2-(benzimidazol-2-yl)-1,10-phenanthrolyl metal (Fe and Co) complexes and their catalytic behaviors toward ethylene oligomerization
文献类型：期刊论文
| 作者 | Zhang, Min1,2; Hao, Peng1,2; Zuo, Weiwei1,2; Jie, Suyun1,2; Sun, Wen-Hua1,2
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| 刊名 | JOURNAL OF ORGANOMETALLIC CHEMISTRY
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| 出版日期 | 2008-02-01 |
| 卷号 | 693期号:3页码:483-491 |
| 关键词 | Iron And Cobalt Tridentate Complexes Ethylene Oligomerization 2-(Benzimidazol-2-yl)-1 10-phenanthrolines |
| ISSN号 | 0022-328X |
| DOI | 10.1016/j.jorganchem.2007.11.020 |
| 英文摘要 | The N boolean AND N boolean AND N-tridentatc metal complexes, LMCl2 (M = Fe or Co; L represents a ligand of 2-(benzimidazol-2-yl)-l, 10-phenanthrolines), were synthesized and fully characterized with spectroscopic and elemental analysis. The single-crystal X-ray crystallographic analyses revealed complex 1a with a distorted octahedron geometry due to incorporating one methanol molecule, and complexes 5a and 9b with a distorted trigonal-bipyramidal geometry. Upon activation with modified methylaluminoxane (MMAO), these complexes showed good to high catalytic activities toward ethylene oligomerization. The detailed investigations were carried out to disclose the influences of various reaction conditions and nature of ligands on their performing activities of metal complexes. (C) 2007 Elsevier B.V. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000253264500014 |
| 出版者 | ELSEVIER SCIENCE SA |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/64851]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Sun, Wen-Hua |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Key Lab Engn, Beijing 100080, Peoples R China 2.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Min,Hao, Peng,Zuo, Weiwei,et al. 2-(benzimidazol-2-yl)-1,10-phenanthrolyl metal (Fe and Co) complexes and their catalytic behaviors toward ethylene oligomerization[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY,2008,693(3):483-491. |
| APA | Zhang, Min,Hao, Peng,Zuo, Weiwei,Jie, Suyun,&Sun, Wen-Hua.(2008).2-(benzimidazol-2-yl)-1,10-phenanthrolyl metal (Fe and Co) complexes and their catalytic behaviors toward ethylene oligomerization.JOURNAL OF ORGANOMETALLIC CHEMISTRY,693(3),483-491. |
| MLA | Zhang, Min,et al."2-(benzimidazol-2-yl)-1,10-phenanthrolyl metal (Fe and Co) complexes and their catalytic behaviors toward ethylene oligomerization".JOURNAL OF ORGANOMETALLIC CHEMISTRY 693.3(2008):483-491. |
入库方式： OAI收割
来源：化学研究所
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