Asymmetric hydration of ortho- or para-substituted styrenes catalyzed by biopolymer-metal complex wool-Pd
文献类型：期刊论文
| 作者 | Wang, Siqian2; Zhang, Zhenfeng3; Chi, Caiqin2; Wu, Guanglong2; Ren, Jianguo1; Wang, Ziwei1; Huang, Meiyu2; Jiang, Yingyan2 |
| 刊名 | REACTIVE & FUNCTIONAL POLYMERS
 |
| 出版日期 | 2008 |
| 卷号 | 68期号:1页码:424-430 |
| 关键词 | Wool-palladium Complex Asymmetric Hydration Ortho-substituted Styrenes Para-substituted Styrenes Enantioselectivity |
| ISSN号 | 1381-5148 |
| DOI | 10.1016/j.reactfunctpolym.2007.06.001 |
| 英文摘要 | A biopolymer complex wool-Pd is found to be efficient catalyst for asymmetric hydration of ortho- or para-substituted styrenes with good to high enantioselectivity by simple and clean process under mild conditions. Chemical and optical yield are affected by some parameters, such as the Pd content in wool-Pd, reaction time, reaction temperature, amount of oxalic acid and water/ethanol. After several-time use of the complex, the chemical and optical yields of the products have no significant changes. Obviously, the methods provide an alternative way to produce chiral benzyl-alcohols by use of asymmetric hydration of ortho- or para-substituted styrenes catalyzed by biopolymer-metal complex wool-Pd. (c) 2007 Published by Elsevier Ltd. |
| 语种 | 英语 |
| WOS记录号 | WOS:000252612800046 |
| 出版者 | ELSEVIER SCIENCE BV |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/64905]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Wang, Ziwei |
| 作者单位 | 1.Shanxi Univ, Coll Chem & Chem Engn, Taiyuan 030006, Peoples R China 2.Chinese Acad Sci, Inst Chem, Grp 4060, Beijing 100080, Peoples R China 3.Henan Normal Univ, Coll Chem & Environm Sci, Xinxiang 453007, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Siqian,Zhang, Zhenfeng,Chi, Caiqin,et al. Asymmetric hydration of ortho- or para-substituted styrenes catalyzed by biopolymer-metal complex wool-Pd[J]. REACTIVE & FUNCTIONAL POLYMERS,2008,68(1):424-430. |
| APA | Wang, Siqian.,Zhang, Zhenfeng.,Chi, Caiqin.,Wu, Guanglong.,Ren, Jianguo.,...&Jiang, Yingyan.(2008).Asymmetric hydration of ortho- or para-substituted styrenes catalyzed by biopolymer-metal complex wool-Pd.REACTIVE & FUNCTIONAL POLYMERS,68(1),424-430. |
| MLA | Wang, Siqian,et al."Asymmetric hydration of ortho- or para-substituted styrenes catalyzed by biopolymer-metal complex wool-Pd".REACTIVE & FUNCTIONAL POLYMERS 68.1(2008):424-430. |
入库方式： OAI收割
来源：化学研究所
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