Pyranylidene carbene complexes from 1-lithio 1,3-dienes and M(CO)(6) (M = Cr, Mo, W): Novel synthesis and demetalation reaction
文献类型：期刊论文
| 作者 | Wang, Qifeng2; Zhang, Wen-Xiong1; Xi, Zhenfeng1,3 |
| 刊名 | ORGANOMETALLICS
 |
| 出版日期 | 2008-08-11 |
| 卷号 | 27期号:15页码:3627-3629 |
| ISSN号 | 0276-7333 |
| DOI | 10.1021/om800565r |
| 英文摘要 | This paper reports a conceptually new and concise synthetic method leading to unprecedented, fully alkyl substituted pyranylidene carbene complexes 2 from M(CO)(6) (M = Cr, Mo, W) and the readily available 1-lithio-1,3-butadiene 1, bearing a leaving group, via an intramolecular trapping of metallaacylate intermediates. These carbenes have been demonstrated to have interesting and unique reactivity. |
| 语种 | 英语 |
| WOS记录号 | WOS:000258226100001 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/64945]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Xi, Zhenfeng |
| 作者单位 | 1.Peking Univ, Coll Chem, Minist Educ, Key Lab Bioorgan Chem & Mol Engn, Beijing 100871, Peoples R China 2.Chinese Acad Sci, Inst Chem, BNLMS, Beijing 100080, Peoples R China 3.Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organomet Chem, Shanghai 200032, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Qifeng,Zhang, Wen-Xiong,Xi, Zhenfeng. Pyranylidene carbene complexes from 1-lithio 1,3-dienes and M(CO)(6) (M = Cr, Mo, W): Novel synthesis and demetalation reaction[J]. ORGANOMETALLICS,2008,27(15):3627-3629. |
| APA | Wang, Qifeng,Zhang, Wen-Xiong,&Xi, Zhenfeng.(2008).Pyranylidene carbene complexes from 1-lithio 1,3-dienes and M(CO)(6) (M = Cr, Mo, W): Novel synthesis and demetalation reaction.ORGANOMETALLICS,27(15),3627-3629. |
| MLA | Wang, Qifeng,et al."Pyranylidene carbene complexes from 1-lithio 1,3-dienes and M(CO)(6) (M = Cr, Mo, W): Novel synthesis and demetalation reaction".ORGANOMETALLICS 27.15(2008):3627-3629. |
入库方式： OAI收割
来源：化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。