Band Gap Tunable, Donor-Acceptor-Donor Charge-Transfer Heteroquinoid-Based Chromophores: Near Infrared Photoluminescence and Electroluminescence
文献类型:期刊论文
作者 | Qian, Gang1,2; Dai, Bo1,2; Luo, Min1,2; Yu, Dengbin1; Zhan, Jie1,2; Zhang, Zhiqiang1; Ma, Dongge1; Wang, Zhi Yuan1,3 |
刊名 | CHEMISTRY OF MATERIALS
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出版日期 | 2008-10-14 |
卷号 | 20期号:19页码:6208-6216 |
ISSN号 | 0897-4756 |
DOI | 10.1021/cm801911n |
英文摘要 | A series of D-pi-A-pi-D type of near-infrared (NIR) fluorescent compounds based on benzobis(thia diazole) and its selenium analogues were synthesized and fully characterized by H-1 and C-13 NMR, high-resolution mass spectrometry, and elemental analysis. The absorption fluorescence, and electrochemical properties were also studied. Photoluminescence of these chromophores ranges from 900 to 1600 nm and their band gaps are between 1.19 and 0.56 eV. Replacing the sulfur by selenium can lead to a red shift for emission and reduce the band gaps further. Interestingly, compound 1 exhibits aggregation-induced emission enhancement effect in the solid state. All-organic light-emitting diodes based on M1 and M2 were made and exclusive NIR emissions above 1 mu m with external quantum efficiency of 0.05% and maximum radiance of 60 mW Sr-1 m(-2) were observed. The longest electroluminesence wavelength reaches 1115 nm. |
语种 | 英语 |
WOS记录号 | WOS:000259871500036 |
出版者 | AMER CHEMICAL SOC |
源URL | [http://ir.iccas.ac.cn/handle/121111/64951] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Wang, Zhi Yuan |
作者单位 | 1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China 2.Chinese Acad Sci, Grad Sch, Changchun 130022, Peoples R China 3.Carleton Univ, Dept Chem, Ottawa, ON K1S 5B6, Canada |
推荐引用方式 GB/T 7714 | Qian, Gang,Dai, Bo,Luo, Min,et al. Band Gap Tunable, Donor-Acceptor-Donor Charge-Transfer Heteroquinoid-Based Chromophores: Near Infrared Photoluminescence and Electroluminescence[J]. CHEMISTRY OF MATERIALS,2008,20(19):6208-6216. |
APA | Qian, Gang.,Dai, Bo.,Luo, Min.,Yu, Dengbin.,Zhan, Jie.,...&Wang, Zhi Yuan.(2008).Band Gap Tunable, Donor-Acceptor-Donor Charge-Transfer Heteroquinoid-Based Chromophores: Near Infrared Photoluminescence and Electroluminescence.CHEMISTRY OF MATERIALS,20(19),6208-6216. |
MLA | Qian, Gang,et al."Band Gap Tunable, Donor-Acceptor-Donor Charge-Transfer Heteroquinoid-Based Chromophores: Near Infrared Photoluminescence and Electroluminescence".CHEMISTRY OF MATERIALS 20.19(2008):6208-6216. |
入库方式: OAI收割
来源:化学研究所
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