Microscopic molecular optics theory of surface second harmonic generation and sum-frequency generation spectroscopy based on the discrete dipole lattice model
文献类型：期刊论文
| 作者 | Zheng, De-Sheng; Wang, Yuan; Liu, An-An; Wang, Hong-Fei |
| 刊名 | INTERNATIONAL REVIEWS IN PHYSICAL CHEMISTRY
 |
| 出版日期 | 2008 |
| 卷号 | 27期号:4页码:629-664 |
| 关键词 | Interface Submonolayer Molecular Orientation Second Harmonic Generation (Shg) Sum Frequency Generation Vibrational Spectroiscopy (Sfg-vs) Maxwell Equations |
| ISSN号 | 0144-235X |
| DOI | 10.1080/01442350802343981 |
| 英文摘要 | The aim of this work is to present a coherent description of the microscopic theory of surface nonlinear optical spectroscopy for solving practical problems in understanding the details of the molecular interface. We review the related issues and show that by following microscopic molecular optics theory, second harmonic generation (SHG), as well as sum-frequency generation vibrational spectroscopy (SFG-VS), radiation from a monolayer or submonolayer can be rigorously treated as the radiation from an induced dipole lattice at the interface. In this approach, the introduction of an infinitesimally thin polarization sheet as in macroscopic theory with the Maxwell equations and the boundary conditions is no longer necessary. As a direct consequence, the ambiguity of the unaccounted dielectric constant of the interfacial layer is no longer an issue. Moreover, the anisotropic two-dimensional microscopic local field factors can be explicitly defined with the linear polarizability tensors of the interfacial molecules. Based on the planewise dipole sum rule in the molecular monolayer, experimental tests of this microscopic treatment with SHG and SFG-VS are discussed. |
| 语种 | 英语 |
| WOS记录号 | WOS:000260163300002 |
| 出版者 | TAYLOR & FRANCIS LTD |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/64983]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Wang, Hong-Fei |
| 作者单位 | Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, State Key Lab Mol React Dynam, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zheng, De-Sheng,Wang, Yuan,Liu, An-An,et al. Microscopic molecular optics theory of surface second harmonic generation and sum-frequency generation spectroscopy based on the discrete dipole lattice model[J]. INTERNATIONAL REVIEWS IN PHYSICAL CHEMISTRY,2008,27(4):629-664. |
| APA | Zheng, De-Sheng,Wang, Yuan,Liu, An-An,&Wang, Hong-Fei.(2008).Microscopic molecular optics theory of surface second harmonic generation and sum-frequency generation spectroscopy based on the discrete dipole lattice model.INTERNATIONAL REVIEWS IN PHYSICAL CHEMISTRY,27(4),629-664. |
| MLA | Zheng, De-Sheng,et al."Microscopic molecular optics theory of surface second harmonic generation and sum-frequency generation spectroscopy based on the discrete dipole lattice model".INTERNATIONAL REVIEWS IN PHYSICAL CHEMISTRY 27.4(2008):629-664. |
入库方式： OAI收割
来源：化学研究所
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