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Chinese Academy of Sciences Institutional Repositories Grid
New second-order nonlinear optical polymers containing the same isolation groups: Optimized syntheses and nonlinear optical properties

文献类型:期刊论文

作者Li, Zhong'an1; Yu, Gui2; Li, Zhen1; Liu, Yunqi2; Ye, Cheng2; Qin, Jingui1
刊名POLYMER
出版日期2008-02-18
卷号49期号:4页码:901-913
关键词Nonlinear Optics Synthesis Second-order Nlo Materials
ISSN号0032-3861
DOI10.1016/j.polymer.2007.12.020
英文摘要Based on control experiments, a new series of second-order nonlinear optical polymers with fluorene moieties as isolation spacers were successfully prepared. In the polymers, the chromophore moieties were embedded into the polymer backbone with one position at the donor side, and another point in the pi bridge. Different acceptors were used to construct the push-pull structure of chromophore moieties, including nitro groups, sulfonyl groups, 3-phenyl-5-isoxazolone, 1,3-diethylthiobarbituric acid and TCF groups. The tested NLO properties of the polymer,,; demonstrated that the isolation groups with big size do not always benefit the resultant NLO effect. Also, for different acceptors, there should be different suitable isolation groups to balance the good and bad effects caused by the introduced isolation spacers. (C) 2007 Elsevier Ltd. All rights reserved.
语种英语
WOS记录号WOS:000253846700011
出版者ELSEVIER SCI LTD
源URL[http://ir.iccas.ac.cn/handle/121111/64985]  
专题中国科学院化学研究所
通讯作者Li, Zhen
作者单位1.Wuhan Univ, Dept Chem, Wuhan 430072, Peoples R China
2.Chinese Acad Sci, Inst Chem, Organ Solids Labs, Beijing 100080, Peoples R China
推荐引用方式
GB/T 7714
Li, Zhong'an,Yu, Gui,Li, Zhen,et al. New second-order nonlinear optical polymers containing the same isolation groups: Optimized syntheses and nonlinear optical properties[J]. POLYMER,2008,49(4):901-913.
APA Li, Zhong'an,Yu, Gui,Li, Zhen,Liu, Yunqi,Ye, Cheng,&Qin, Jingui.(2008).New second-order nonlinear optical polymers containing the same isolation groups: Optimized syntheses and nonlinear optical properties.POLYMER,49(4),901-913.
MLA Li, Zhong'an,et al."New second-order nonlinear optical polymers containing the same isolation groups: Optimized syntheses and nonlinear optical properties".POLYMER 49.4(2008):901-913.

入库方式: OAI收割

来源:化学研究所

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