Solvent effect on the film formation and the stability of the surface properties of poly(methyl methacrylate) end-capped with fluorinated units
文献类型：期刊论文
| 作者 | Wang, Xiaofang1; Ni, Huagang1; Xue, Dongwu1; Wang, Xinping1; Feng, Ran-ran2; Wang, Hong-fei2 |
| 刊名 | JOURNAL OF COLLOID AND INTERFACE SCIENCE
 |
| 出版日期 | 2008-05-15 |
| 卷号 | 321期号:2页码:373-383 |
| 关键词 | Hydrophobic Surface Perfluoroalkyl Side Chain Surface Structure End-capped Poly(Methyl Methacrylate) Solvent Effect |
| ISSN号 | 0021-9797 |
| DOI | 10.1016/j.jcis.2008.02.018 |
| 英文摘要 | The surface structure and stability (the resistance to surface reconstruction) of end-capped poly(methyl methacrylate) films were greatly affected by the solvents used for film preparation. Films of end-capped PMMA with about four 2-perfluorooctylethyl methacrylate units cast with benzotrifluoride solution exhibited excellent stability and resistance to polar environments compared with those cast with cyclohexanone and toluene solutions. The observed difference in stability between these fluorinated surfaces is attributed to their surface microstructures formed during the film formation processes, which are closely related to the associative behavior of the end-capped PMMA in the solution. A relatively perfect close-packed and well-ordered structure of the perfluoroalkyl side chains at the surface of the PMMA(857)-ec-FMA(3.3) film was formed when the film was cast with benzotrifluoride solution, in which only unimers existed. This study indicates that such a solvent effect may be used to promote the formation of a well-ordered packing structure of the fluorinated moieties at the film surface. The ordering of the packing structure is to a certain extent more important than the content of the fluorinated moieties at the surface for improving the surface stability. (c) 2008 Elsevier Inc. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000255134300017 |
| 出版者 | ACADEMIC PRESS INC ELSEVIER SCIENCE |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/65051]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Wang, Xinping |
| 作者单位 | 1.Zhejiang Sci Tech Univ, Dept Chem, Key Lab Adv Text Mat & Mfg Technol, Educ Minist, Hangzhou, Peoples R China 2.Chinese Acad Sci, Inst Chem, State Key Lab Mol React Dynam, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Xiaofang,Ni, Huagang,Xue, Dongwu,et al. Solvent effect on the film formation and the stability of the surface properties of poly(methyl methacrylate) end-capped with fluorinated units[J]. JOURNAL OF COLLOID AND INTERFACE SCIENCE,2008,321(2):373-383. |
| APA | Wang, Xiaofang,Ni, Huagang,Xue, Dongwu,Wang, Xinping,Feng, Ran-ran,&Wang, Hong-fei.(2008).Solvent effect on the film formation and the stability of the surface properties of poly(methyl methacrylate) end-capped with fluorinated units.JOURNAL OF COLLOID AND INTERFACE SCIENCE,321(2),373-383. |
| MLA | Wang, Xiaofang,et al."Solvent effect on the film formation and the stability of the surface properties of poly(methyl methacrylate) end-capped with fluorinated units".JOURNAL OF COLLOID AND INTERFACE SCIENCE 321.2(2008):373-383. |
入库方式： OAI收割
来源：化学研究所
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