Hydrothermal synthesis, structure and antiferromagnetism of Mn[P2O5(OH)(2)]
文献类型：期刊论文
| 作者 | Yang, Tao1; Zhang, Yan2; Xiong, Ming3; Liao, Fuhui1; Lin, Jianhua1 |
| 刊名 | SOLID STATE SCIENCES
 |
| 出版日期 | 2008-12-01 |
| 卷号 | 10期号:12页码:1886-1890 |
| 关键词 | Manganese Phosphate Hydrothermal Structure Antiferromagnetism |
| ISSN号 | 1293-2558 |
| DOI | 10.1016/j.solidstatesciences.2008.03.021 |
| 英文摘要 | A new manganese diphosphate Mn[P2O5(OH)(2)] (1) has been hydrothermally synthesized and structurally characterized by single-crystal X-ray diffraction. It crystallizes in the monoclinic space group C2/c with the lattice: a = 7.1487(14) angstrom, b = 7.9804(16) angstrom, c = 9.4812(19) angstrom, beta = 101.18(3)degrees, V = 530.63(18) angstrom(3), and Z = 4. Mn2+ is coordinated in a typical octahedral environment and the phosphates are dimerized as P2O7 groups. Each MnO6 is surrounded by Six PO4 and each PO4 group (as a part Of P2O7) is linked with three MnO6, giving an Mn:P ratio of 1:2. Upon heating, the 3D structure of 1 keeps intact until the dehydration, which occurs at 390 degrees C and leads to a known phase Mn2P4O12. The magnetic interactions between Mn2+ ions transmitted via O-P-O are antiferromagnetic (AFM) and 1 shows an AFM long-range ordering at 3.5 K. (C) 2008 Elsevier Masson SAS. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000262236800035 |
| 出版者 | ELSEVIER SCIENCE BV |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/65117]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Lin, Jianhua |
| 作者单位 | 1.Peking Univ, Beijing Natl Lab Mol Sci, State Key Lab Rare Earth Mat Chem & Applicat, Coll Chem & Mol Engn, Beijing 100871, Peoples R China 2.Peking Univ, Dept Phys, Beijing 100871, Peoples R China 3.China Univ Geosci, Xray Lab, Beijing 100083, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yang, Tao,Zhang, Yan,Xiong, Ming,et al. Hydrothermal synthesis, structure and antiferromagnetism of Mn[P2O5(OH)(2)][J]. SOLID STATE SCIENCES,2008,10(12):1886-1890. |
| APA | Yang, Tao,Zhang, Yan,Xiong, Ming,Liao, Fuhui,&Lin, Jianhua.(2008).Hydrothermal synthesis, structure and antiferromagnetism of Mn[P2O5(OH)(2)].SOLID STATE SCIENCES,10(12),1886-1890. |
| MLA | Yang, Tao,et al."Hydrothermal synthesis, structure and antiferromagnetism of Mn[P2O5(OH)(2)]".SOLID STATE SCIENCES 10.12(2008):1886-1890. |
入库方式： OAI收割
来源：化学研究所
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