HeI photoelectron spectra and valence synchrotron photoionization for XC(O)SCl (X = F, Cl) compounds
文献类型：期刊论文
| 作者 | Gerones, Mariana1; Erben, Mauricio F.1; Romano, Rosana M.1; Della Vedova, Carlos O.1; Yao, Li3; Ge, Maofa2,3 |
| 刊名 | JOURNAL OF PHYSICAL CHEMISTRY A
 |
| 出版日期 | 2008-03-20 |
| 卷号 | 112期号:11页码:2228-2234 |
| ISSN号 | 1089-5639 |
| DOI | 10.1021/jp7101034 |
| 英文摘要 | Small penta-atomic molecules like FC(O)SCl and ClC(O)SCl have been analyzed by using both photoelectron spectroscopy (PES) and results derived from the use of synchrotron radiation in the same energy range. For this second experiment total ion yield (TIY), photoelectron photoion coincidence (PEPICO), and partial ion yield (PIY) spectra have been recorded. This set of data together with results obtained by computational chemistry allow us to study electronic properties and the ionization channels of both species. Thus, whereas the photodissociation behavior of FC(O)SCl can be divided into three well-defined energy regions, the fragmentation dynamics of ClC(O)SCl seems to be more complex. Nevertheless, simultaneous evaluation of the PES and valence synchrotron photoionization studies helps to clarify the molecular ionization processes. |
| 语种 | 英语 |
| WOS记录号 | WOS:000253946100011 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/65197]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Ge, Maofa |
| 作者单位 | 1.Natl Univ La Plata, Fac Ciencias Exactas, Dept Quim, CEQUINOR CONICET, RA-1900 La Plata, Argentina 2.UNLP CIC CONICET, LaSeISiC, Lab Serv Ind & Sistema Cientifico, RA-1903 Gonnet, Argentina 3.Chinese Acad Sci, Inst Chem, BNLMS, State Key Lab Struct Chem Unstable & Stable Speci, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Gerones, Mariana,Erben, Mauricio F.,Romano, Rosana M.,et al. HeI photoelectron spectra and valence synchrotron photoionization for XC(O)SCl (X = F, Cl) compounds[J]. JOURNAL OF PHYSICAL CHEMISTRY A,2008,112(11):2228-2234. |
| APA | Gerones, Mariana,Erben, Mauricio F.,Romano, Rosana M.,Della Vedova, Carlos O.,Yao, Li,&Ge, Maofa.(2008).HeI photoelectron spectra and valence synchrotron photoionization for XC(O)SCl (X = F, Cl) compounds.JOURNAL OF PHYSICAL CHEMISTRY A,112(11),2228-2234. |
| MLA | Gerones, Mariana,et al."HeI photoelectron spectra and valence synchrotron photoionization for XC(O)SCl (X = F, Cl) compounds".JOURNAL OF PHYSICAL CHEMISTRY A 112.11(2008):2228-2234. |
入库方式： OAI收割
来源：化学研究所
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