ATRP of 3-(triethoxysilyl)propyl methacrylate and preparation of "stable" gelable block copolymers
文献类型：期刊论文
| 作者 | Xiong, Ming; Zhang, Ke; Chen, Yongming |
| 刊名 | EUROPEAN POLYMER JOURNAL
 |
| 出版日期 | 2008-11-01 |
| 卷号 | 44期号:11页码:3835-3841 |
| 关键词 | Atom Transfer Radical Polymerization Block Copolymers Controlled Polymerization Self-assembly |
| ISSN号 | 0014-3057 |
| DOI | 10.1016/j.eurpolymj.2008.07.052 |
| 英文摘要 | ATRP of a gelable monomer, 3-(triethoxysilyl)propyl methacrylate (TESPMA), mediated by CuBr/N,N,N',N '',N ''-pentamethyldiethylenetriamine (PMDETA) using ethyl 2-bromoisobutyrate (2-EBiB) as initiator was studied. The results indicate that polymerization follows the first-order kinetic. PolyTESPMA (PTESPMA) is much more stable to moisture which is important for exploring the properties of its block copolymer. A series of PEO-b-PTESPMA block copolymers with different composition were prepared. Self-assembly of PEO-b-PTESPMA has also been explored in a mixture of methanol and water and polymeric vesicles have been obtained. By introducing the gelation catalyst, the block copolymer vesicles can be stabilized by the silica networks. (c) 2008 Elsevier Ltd. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000261722600053 |
| 出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/65237]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Chen, Yongming |
| 作者单位 | Chinese Acad Sci, Inst Chem, State Key Lab Polymer Phys & Chem, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xiong, Ming,Zhang, Ke,Chen, Yongming. ATRP of 3-(triethoxysilyl)propyl methacrylate and preparation of "stable" gelable block copolymers[J]. EUROPEAN POLYMER JOURNAL,2008,44(11):3835-3841. |
| APA | Xiong, Ming,Zhang, Ke,&Chen, Yongming.(2008).ATRP of 3-(triethoxysilyl)propyl methacrylate and preparation of "stable" gelable block copolymers.EUROPEAN POLYMER JOURNAL,44(11),3835-3841. |
| MLA | Xiong, Ming,et al."ATRP of 3-(triethoxysilyl)propyl methacrylate and preparation of "stable" gelable block copolymers".EUROPEAN POLYMER JOURNAL 44.11(2008):3835-3841. |
入库方式： OAI收割
来源：化学研究所
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