Aqueous-phase biphasic dehydroaromatization of bio-derived limonene into p-cymene by soluble Pd nanocluster catalysts
文献类型：期刊论文
| 作者 | Zhao, Chen2; Gan, Weijia2; Fan, Xiaobing2; Cai, Zhipeng2; Dyson, Paul J.; Kou, Yuan2 |
| 刊名 | JOURNAL OF CATALYSIS
 |
| 出版日期 | 2008-03-10 |
| 卷号 | 254期号:2页码:244-250 |
| 关键词 | Limonene P-cymene Dehydroaromatization Palladium Nanoparticles Biphasic Catalysis Terpene Poly(N-vinyl-2-pyrrolidone) Biomass |
| ISSN号 | 0021-9517 |
| DOI | 10.1016/j.jcat.2008.01.003 |
| 英文摘要 | A biphasic approach to the dehydroaromatization of bioderived limonene into water-insoluble p-cymene using soluble Pd nanoparticle catalysts in an aqueous phase (>= 150 degrees C, 2 bar H-2) was successfully achieved with a conversion of 93% and a selectivity of 82%. The Pd nanoparticles, operating under forcing conditions (180 degrees C, 2 bar H-2), can be recycled at least four times without noticeable degradation. The effects of temperature, pressure, reaction time, pH, catalyst concentration, metal type, the type and amount of polymer stabilizer, and the preparation method were systematically investigated to optimize the process and provide insight into the mechanisms involved. (C) 2008 Elsevier Inc. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000255533700010 |
| 出版者 | ACADEMIC PRESS INC ELSEVIER SCIENCE |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/65309]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Dyson, Paul J. |
| 作者单位 | 1.Ecole Polytech Fed Lausanne, Inst Sci Ingn Chim, CH-1015 Lausanne, Switzerland 2.Peking Univ, Coll Chem & Mol Engn, PKU Green Chem Ctr, Beijing Natl Lab Mol Sci, Beijing 100871, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhao, Chen,Gan, Weijia,Fan, Xiaobing,et al. Aqueous-phase biphasic dehydroaromatization of bio-derived limonene into p-cymene by soluble Pd nanocluster catalysts[J]. JOURNAL OF CATALYSIS,2008,254(2):244-250. |
| APA | Zhao, Chen,Gan, Weijia,Fan, Xiaobing,Cai, Zhipeng,Dyson, Paul J.,&Kou, Yuan.(2008).Aqueous-phase biphasic dehydroaromatization of bio-derived limonene into p-cymene by soluble Pd nanocluster catalysts.JOURNAL OF CATALYSIS,254(2),244-250. |
| MLA | Zhao, Chen,et al."Aqueous-phase biphasic dehydroaromatization of bio-derived limonene into p-cymene by soluble Pd nanocluster catalysts".JOURNAL OF CATALYSIS 254.2(2008):244-250. |
入库方式： OAI收割
来源：化学研究所
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