Four isomorphous phosphates AM(3)P(4)O(14) (A = Sr, Ba; M = Co, Mn) with antiferromagnetic-antiferromagnetic-ferromagnetic trimerized chains, showing 1/3 quantum magnetization plateaus only in the manganese(II) system
文献类型：期刊论文
| 作者 | Yang, Tao1; Zhang, Yan2; Yang, Sihai1; Li, Guobao1; Xiong, Ming3; Liao, Fuhui1; Lin, Jianhua1 |
| 刊名 | INORGANIC CHEMISTRY
 |
| 出版日期 | 2008-04-07 |
| 卷号 | 47期号:7页码:2562-2568 |
| ISSN号 | 0020-1669 |
| DOI | 10.1021/ic702346e |
| 英文摘要 | The four new phosphates BaCO3P4O14 (1), SrCO3P4O14 (2), BaMn3P4O14 (3), and SrMn3P4O14 (4) were hydrothermally synthesized and characterized structurally and magnetically. They are isostructural with ANi(3)P(4)O(14) (A = Ca, Sr, Pb, Ba), crystallizing in the monoclinic space group P2(1)/c. The CoO6 (or MnO6) octahedra share edges to from zigzag chains along the b axis, which are further interconnected by P2O7 groups into a three-dimensional structure. Preliminary magnetic measurements on powder samples indicate that 1, 2, and 4 are spin-canted antiferromagnets and 3 is a pure antiferromagnet at low field; long-range orderings were established respectively at T-critical approximate to 8.2 K for 1, 6.5 K for 2, and 2.6 K for both 3 and 4; field-induced spin-flop-like transitions occur respectively at H-c approximate to 25 kOe for 1, 4 kOe for 2, 3 kOe for 3, and 0.7 kOe for 4. Interestingly, together with the known Ni analogues, they all apply the same antiferromagnetic-antiterromagnetic-ferromagnetic (AAF) trimerized chain model, whereas the 1/3 quantum magnetization plateau only appears in the Mn system. By qualitative analysis, we conclude that the appearance of quantum magnetization plateaus in the AAF chain compounds requires both good 1 D characteristics and strong AF intrachain interactions. |
| 语种 | 英语 |
| WOS记录号 | WOS:000254603900045 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/65339]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Lin, Jianhua |
| 作者单位 | 1.Peking Univ, Coll Chem & Mol Engn, State Key Lab Rare Earth Mat Chem & Applicat, Beijing Natl Lab Mol Sci, Beijing 100871, Peoples R China 2.Peking Univ, Dept Phys, Beijing 100871, Peoples R China 3.China Univ Geosci, Xray Lab, Beijing 100083, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yang, Tao,Zhang, Yan,Yang, Sihai,et al. Four isomorphous phosphates AM(3)P(4)O(14) (A = Sr, Ba; M = Co, Mn) with antiferromagnetic-antiferromagnetic-ferromagnetic trimerized chains, showing 1/3 quantum magnetization plateaus only in the manganese(II) system[J]. INORGANIC CHEMISTRY,2008,47(7):2562-2568. |
| APA | Yang, Tao.,Zhang, Yan.,Yang, Sihai.,Li, Guobao.,Xiong, Ming.,...&Lin, Jianhua.(2008).Four isomorphous phosphates AM(3)P(4)O(14) (A = Sr, Ba; M = Co, Mn) with antiferromagnetic-antiferromagnetic-ferromagnetic trimerized chains, showing 1/3 quantum magnetization plateaus only in the manganese(II) system.INORGANIC CHEMISTRY,47(7),2562-2568. |
| MLA | Yang, Tao,et al."Four isomorphous phosphates AM(3)P(4)O(14) (A = Sr, Ba; M = Co, Mn) with antiferromagnetic-antiferromagnetic-ferromagnetic trimerized chains, showing 1/3 quantum magnetization plateaus only in the manganese(II) system".INORGANIC CHEMISTRY 47.7(2008):2562-2568. |
入库方式： OAI收割
来源：化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。