Aerosol assisted synthesis of silica/phenolic resin composite mesoporous hollow spheres
文献类型:期刊论文
作者 | Yu, Xianglin1; Ding, Shujiang1; Meng, Zhaokai1; Liu, Jiguang1; Qu, Xiaozhong1; Lu, Yunfeng2; Yang, Zhenzhong1![]() |
刊名 | COLLOID AND POLYMER SCIENCE
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出版日期 | 2008-12-01 |
卷号 | 286期号:12页码:1361-1368 |
关键词 | Hollow Spheres Mesoporous Carbon Composite Template |
ISSN号 | 0303-402X |
DOI | 10.1007/s00396-008-1904-0 |
英文摘要 | Hollow spheres of phenolic resin/silica composite are synthesized by macroscopic phase separation of a sorbitan monooleate surfactant Span 80 during aerosol-assisted spraying. The cavity can be evolved from multiple compartments to single hollow cavity with the increase of Span 80 content. The composite shell becomes mesoporous due to the release of small molecules after thermal treatment above 350 degrees C. After further thermal treatment at a higher temperature for example 900 degrees C in nitrogen or 1,450 degrees C in argon, the carbon/silica composite hollow spheres or crystalline silicon carbide hollow spheres are derived, respectively. Compared to the pure phenolic resin-based carbon spheres, thermal stability of the carbon-based composite spheres in air is essentially improved by the introduction of inorganic component silica. The carbon-based composite hollow spheres combine both performances of easy mass transportation through macropores and high specific surface area of mesopores, which will be promising to support catalysts for fuel cells. |
语种 | 英语 |
WOS记录号 | WOS:000258931900003 |
出版者 | SPRINGER |
源URL | [http://ir.iccas.ac.cn/handle/121111/65397] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Liu, Jiguang |
作者单位 | 1.Chinese Acad Sci, Inst Chem, State Key Lab Polymer Phys & Chem, Beijing 100190, Peoples R China 2.Univ Calif Los Angeles, Chem & Biomol Engn Dept, Los Angeles, CA 90095 USA |
推荐引用方式 GB/T 7714 | Yu, Xianglin,Ding, Shujiang,Meng, Zhaokai,et al. Aerosol assisted synthesis of silica/phenolic resin composite mesoporous hollow spheres[J]. COLLOID AND POLYMER SCIENCE,2008,286(12):1361-1368. |
APA | Yu, Xianglin.,Ding, Shujiang.,Meng, Zhaokai.,Liu, Jiguang.,Qu, Xiaozhong.,...&Yang, Zhenzhong.(2008).Aerosol assisted synthesis of silica/phenolic resin composite mesoporous hollow spheres.COLLOID AND POLYMER SCIENCE,286(12),1361-1368. |
MLA | Yu, Xianglin,et al."Aerosol assisted synthesis of silica/phenolic resin composite mesoporous hollow spheres".COLLOID AND POLYMER SCIENCE 286.12(2008):1361-1368. |
入库方式: OAI收割
来源:化学研究所
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