中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Aerosol assisted synthesis of silica/phenolic resin composite mesoporous hollow spheres

文献类型:期刊论文

作者Yu, Xianglin1; Ding, Shujiang1; Meng, Zhaokai1; Liu, Jiguang1; Qu, Xiaozhong1; Lu, Yunfeng2; Yang, Zhenzhong1
刊名COLLOID AND POLYMER SCIENCE
出版日期2008-12-01
卷号286期号:12页码:1361-1368
关键词Hollow Spheres Mesoporous Carbon Composite Template
ISSN号0303-402X
DOI10.1007/s00396-008-1904-0
英文摘要Hollow spheres of phenolic resin/silica composite are synthesized by macroscopic phase separation of a sorbitan monooleate surfactant Span 80 during aerosol-assisted spraying. The cavity can be evolved from multiple compartments to single hollow cavity with the increase of Span 80 content. The composite shell becomes mesoporous due to the release of small molecules after thermal treatment above 350 degrees C. After further thermal treatment at a higher temperature for example 900 degrees C in nitrogen or 1,450 degrees C in argon, the carbon/silica composite hollow spheres or crystalline silicon carbide hollow spheres are derived, respectively. Compared to the pure phenolic resin-based carbon spheres, thermal stability of the carbon-based composite spheres in air is essentially improved by the introduction of inorganic component silica. The carbon-based composite hollow spheres combine both performances of easy mass transportation through macropores and high specific surface area of mesopores, which will be promising to support catalysts for fuel cells.
语种英语
WOS记录号WOS:000258931900003
出版者SPRINGER
源URL[http://ir.iccas.ac.cn/handle/121111/65397]  
专题中国科学院化学研究所
通讯作者Liu, Jiguang
作者单位1.Chinese Acad Sci, Inst Chem, State Key Lab Polymer Phys & Chem, Beijing 100190, Peoples R China
2.Univ Calif Los Angeles, Chem & Biomol Engn Dept, Los Angeles, CA 90095 USA
推荐引用方式
GB/T 7714
Yu, Xianglin,Ding, Shujiang,Meng, Zhaokai,et al. Aerosol assisted synthesis of silica/phenolic resin composite mesoporous hollow spheres[J]. COLLOID AND POLYMER SCIENCE,2008,286(12):1361-1368.
APA Yu, Xianglin.,Ding, Shujiang.,Meng, Zhaokai.,Liu, Jiguang.,Qu, Xiaozhong.,...&Yang, Zhenzhong.(2008).Aerosol assisted synthesis of silica/phenolic resin composite mesoporous hollow spheres.COLLOID AND POLYMER SCIENCE,286(12),1361-1368.
MLA Yu, Xianglin,et al."Aerosol assisted synthesis of silica/phenolic resin composite mesoporous hollow spheres".COLLOID AND POLYMER SCIENCE 286.12(2008):1361-1368.

入库方式: OAI收割

来源:化学研究所

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