Aggregation properties of cationic gemini surfactants with dihydroxyethylamino headgroups in aqueous solution
文献类型：期刊论文
| 作者 | Huang, Xu; Han, Yuchun; Wang, Yingxiong; Cao, Meiwen; Wang, Yilin |
| 刊名 | COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
 |
| 出版日期 | 2008-07-15 |
| 卷号 | 325期号:1-2页码:26-32 |
| 关键词 | Gemini Surfactant Cmc Spacer Length Hydrogen Bond |
| ISSN号 | 0927-7757 |
| DOI | 10.1016/j.colsurfa.2008.04.028 |
| 英文摘要 | A series of cationic gemini surfactants, alkanediyl-alpha,omega-bis[di(2-hydroxylethyl) dodecylammonium] dibromide (abbreviated as 12-s-12 (OH), with s=4, 6, 8 and 10 methylenes) have been synthesized, and their aggregation properties in aqueous solution have been studied by surface tension, electrical conductivity, isothermal titration calorimetry, H-1 NMR, dynamic light scattering, and transmission electron microscopy. Two critical aggregation concentrations are observed for these surfactants. These surfactants start to form dimers at concentrations well below their critical micelle concentrations (CMC). Above the CMC, these surfactants can form both micelles and vesicles spontaneously with a micelle-to-vesicle transition. The hydrogen bond among the OH groups of headgroups and water molecules as well as the strong hydrophobic interaction among the hydrocarbon side chains should be the main origins for these unique aggregation behaviors of these gemini surfactants. (C) 2008 Elsevier B.V. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000259077800005 |
| 出版者 | ELSEVIER SCIENCE BV |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/65439]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Wang, Yilin |
| 作者单位 | Chinese Acad Sci, Inst Chem, Key Lab Colloid & Interface Sci, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Huang, Xu,Han, Yuchun,Wang, Yingxiong,et al. Aggregation properties of cationic gemini surfactants with dihydroxyethylamino headgroups in aqueous solution[J]. COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS,2008,325(1-2):26-32. |
| APA | Huang, Xu,Han, Yuchun,Wang, Yingxiong,Cao, Meiwen,&Wang, Yilin.(2008).Aggregation properties of cationic gemini surfactants with dihydroxyethylamino headgroups in aqueous solution.COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS,325(1-2),26-32. |
| MLA | Huang, Xu,et al."Aggregation properties of cationic gemini surfactants with dihydroxyethylamino headgroups in aqueous solution".COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS 325.1-2(2008):26-32. |
入库方式： OAI收割
来源：化学研究所
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