Isothermal differential scanning calorimetry study of the cure kinetics of a novel aromatic maleimide with an acetylene terminal
文献类型：期刊论文
| 作者 | Luo, Zhenhua1; Wei, Liuhe2; Li, Wanwan1; Liu, Feng1; Zhao, Tong1 |
| 刊名 | JOURNAL OF APPLIED POLYMER SCIENCE
 |
| 出版日期 | 2008-07-05 |
| 卷号 | 109期号:1页码:525-529 |
| 关键词 | Thermosets Curing Of Polymers Differential Scanning Calorimetry (Dsc) Kinetics |
| ISSN号 | 0021-8995 |
| DOI | 10.1002/app.28090 |
| 英文摘要 | An isothermal differential scanning calorimetry (DSC) study on the cure kinetics was performed on N-(3-acetylenephenyl)maleimide (3-APMI) monomer to determine a suitable cure model. The 3-APMI monomer reported in our prior article was a novel aromatic maleimide monomer with an acetylene terminal that would be an ideal candidate for heat-resistant composites. The isothermal DSC study was carried out in the temperature range 150-200 degrees C. Although the cure temperatures were different, the shapes of the conversion curves were similar, and all of the cure reactions could be described by an nth-order kinetic model. In particular, the cure reaction at the initial stage was a first-order kinetic reaction. The cure kinetic parameters of the 3-APMI monomer, including the reaction model, activation energy, and frequency factor, were determined. This information was very useful for defining the process parameters, final properties, and quality control of the cured 3-APMI monomer. (c) 2008 Wiley Periodicals, Inc. |
| 语种 | 英语 |
| WOS记录号 | WOS:000255626700067 |
| 出版者 | JOHN WILEY & SONS INC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/65461]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Zhao, Tong |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China 2.Zhengzhou Univ, Sch Chem Engn, Zhengzhou 450002, Peoples R China |
| 推荐引用方式 GB/T 7714 | Luo, Zhenhua,Wei, Liuhe,Li, Wanwan,et al. Isothermal differential scanning calorimetry study of the cure kinetics of a novel aromatic maleimide with an acetylene terminal[J]. JOURNAL OF APPLIED POLYMER SCIENCE,2008,109(1):525-529. |
| APA | Luo, Zhenhua,Wei, Liuhe,Li, Wanwan,Liu, Feng,&Zhao, Tong.(2008).Isothermal differential scanning calorimetry study of the cure kinetics of a novel aromatic maleimide with an acetylene terminal.JOURNAL OF APPLIED POLYMER SCIENCE,109(1),525-529. |
| MLA | Luo, Zhenhua,et al."Isothermal differential scanning calorimetry study of the cure kinetics of a novel aromatic maleimide with an acetylene terminal".JOURNAL OF APPLIED POLYMER SCIENCE 109.1(2008):525-529. |
入库方式： OAI收割
来源：化学研究所
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