Energy-Level and Molecular Engineering of Organic D-pi-A Sensitizers in Dye-Sensitized Solar Cells
文献类型:期刊论文
作者 | Xu, Mingfei1; Li, Renzhi1; Pootrakulchote, Nuttapol2; Shi, Dong1; Guo, Jin1; Yi, Zhihui1; Zakeeruddin, Shaik M.2; Graetzel, Michael2; Wang, Peng1 |
刊名 | JOURNAL OF PHYSICAL CHEMISTRY C |
出版日期 | 2008-12-11 |
卷号 | 112期号:49页码:19770-19776 |
ISSN号 | 1932-7447 |
DOI | 10.1021/jp808275z |
英文摘要 | A series of organic D-pi-A sensitizers composed of different triarylamine donors in conjugation with the thienothiophene unit and cyanoacrylic acid as an acceptor has been synthesized at a moderate yield. Through tuning the number of methoxy substituents on the triphenylamine donor, we have gradually red-shifted the absorption of sensitizers to enhance device efficiencies. Further molecular engineering by the substitution of two hexyloxy chains in place of the methoxy groups allows fabricating a solvent-free dye-sensitized solar cell with a power conversion efficiency of 7.05% measured under the air mass 1.5 global sunlight. Time- and frequency-domain photoelectrical techniques have been employed to scrutinize the aliphatic chain effects with a close inspection on effective electron lifetime, diffusion coefficient, and diffusion length. |
语种 | 英语 |
出版者 | AMER CHEMICAL SOC |
WOS记录号 | WOS:000261426600086 |
源URL | [http://ir.iccas.ac.cn/handle/121111/65467] |
专题 | 中国科学院化学研究所 |
通讯作者 | Wang, Peng |
作者单位 | 1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China 2.Swiss Fed Inst Technol, Lab Photon & Interfaces, CH-1015 Lausanne, Switzerland |
推荐引用方式 GB/T 7714 | Xu, Mingfei,Li, Renzhi,Pootrakulchote, Nuttapol,et al. Energy-Level and Molecular Engineering of Organic D-pi-A Sensitizers in Dye-Sensitized Solar Cells[J]. JOURNAL OF PHYSICAL CHEMISTRY C,2008,112(49):19770-19776. |
APA | Xu, Mingfei.,Li, Renzhi.,Pootrakulchote, Nuttapol.,Shi, Dong.,Guo, Jin.,...&Wang, Peng.(2008).Energy-Level and Molecular Engineering of Organic D-pi-A Sensitizers in Dye-Sensitized Solar Cells.JOURNAL OF PHYSICAL CHEMISTRY C,112(49),19770-19776. |
MLA | Xu, Mingfei,et al."Energy-Level and Molecular Engineering of Organic D-pi-A Sensitizers in Dye-Sensitized Solar Cells".JOURNAL OF PHYSICAL CHEMISTRY C 112.49(2008):19770-19776. |
入库方式: OAI收割
来源:化学研究所
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