中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Solvent-free synthesis of substituted ureas from CO2 and amines with a functional ionic liquid as the catalyst

文献类型:期刊论文

作者Jiang, Tao; Ma, Xiumin; Zhou, Yinxi; Liang, Shuguang; Zhang, Jicheng; Han, Buxing
刊名GREEN CHEMISTRY
出版日期2008
卷号10期号:4页码:465-469
ISSN号1463-9262
DOI10.1039/b717868a
英文摘要The synthesis of disubstituted ureas from amines and CO2 were carried out using a basic ionic liquid (IL) 1-n-butyl-3-methyl imidazolium hydroxide ([Bmim] OH) as the catalyst. The effects of reaction time, amount of [Bmim] OH, reaction temperature, pressure, and solvent on yields of the products were investigated. The results indicated that aliphatic amines, cyclohexylamine, and benzylamine could be converted to the corresponding ureas selectively in moderate yields under solvent-free conditions without using any dehydrating regent. The IL could be reused after a simple separation procedure.
语种英语
WOS记录号WOS:000254443000019
出版者ROYAL SOC CHEMISTRY
源URL[http://ir.iccas.ac.cn/handle/121111/65591]  
专题中国科学院化学研究所
通讯作者Jiang, Tao
作者单位Chinese Acad Sci, Inst Chem, Ctr Mol Sci, BNLMS, Beijing 100080, Peoples R China
推荐引用方式
GB/T 7714
Jiang, Tao,Ma, Xiumin,Zhou, Yinxi,et al. Solvent-free synthesis of substituted ureas from CO2 and amines with a functional ionic liquid as the catalyst[J]. GREEN CHEMISTRY,2008,10(4):465-469.
APA Jiang, Tao,Ma, Xiumin,Zhou, Yinxi,Liang, Shuguang,Zhang, Jicheng,&Han, Buxing.(2008).Solvent-free synthesis of substituted ureas from CO2 and amines with a functional ionic liquid as the catalyst.GREEN CHEMISTRY,10(4),465-469.
MLA Jiang, Tao,et al."Solvent-free synthesis of substituted ureas from CO2 and amines with a functional ionic liquid as the catalyst".GREEN CHEMISTRY 10.4(2008):465-469.

入库方式: OAI收割

来源:化学研究所

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