Na-8[Cr4B12P8O44(OH)(4)][P2O7]center dot nH(2)O: A 3D borophosphate framework with spherical cages
文献类型：期刊论文
| 作者 | Yang, Tao1; Sun, Junliang2; Li, Guobao1; Eriksson, Lars2; Zou, Xiaodong2; Liao, Fuhui1; Lin, Jianhua1 |
| 刊名 | CHEMISTRY-A EUROPEAN JOURNAL
 |
| 出版日期 | 2008 |
| 卷号 | 14期号:24页码:7212-7217 |
| 关键词 | Borophosphate Cage Compounds Chromium Structure Elucidation |
| ISSN号 | 0947-6539 |
| DOI | 10.1002/chem.200800789 |
| 英文摘要 | A chromium borophosphate-phosphate (Na-8[Cr4B12P8O44(OH)(4)]-[P2O7]center dot nH(2)O,1), which has an unusual 3D framework structure, was synthesized under hydrothermal conditions. The framework consists of spherical cages composed of CrO6, PO4, BO4, and BO3 polyhedra. The cages are located at the vertices and the body center of the cubic cell and are interconnected through 12-membered-ring windows along the {111} direction. The actual framework structure is very complex, but the description can be simplified by using the 5-connected fundamental building cluster [CrP5B3O24](11-). In addition, 1 represents the first borate-rich borophosphate that contains a 3D borophosphate partial framework (infinity(3)- [B3P2O11(OH)]) in which the fundamental building unit is an oB dreier single ring (Delta 4(sic):(sic) |
| 语种 | 英语 |
| WOS记录号 | WOS:000258801500015 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/65633]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Lin, Jianhua |
| 作者单位 | 1.Peking Univ, Coll Chem & Mol Engn, State Key Lab Rare Earth Mat Chem & Applicat, Beijing Natl Lab Mol Sci, Beijing 100871, Peoples R China 2.Stockholm Univ, S-10691 Stockholm, Sweden |
| 推荐引用方式 GB/T 7714 | Yang, Tao,Sun, Junliang,Li, Guobao,et al. Na-8[Cr4B12P8O44(OH)(4)][P2O7]center dot nH(2)O: A 3D borophosphate framework with spherical cages[J]. CHEMISTRY-A EUROPEAN JOURNAL,2008,14(24):7212-7217. |
| APA | Yang, Tao.,Sun, Junliang.,Li, Guobao.,Eriksson, Lars.,Zou, Xiaodong.,...&Lin, Jianhua.(2008).Na-8[Cr4B12P8O44(OH)(4)][P2O7]center dot nH(2)O: A 3D borophosphate framework with spherical cages.CHEMISTRY-A EUROPEAN JOURNAL,14(24),7212-7217. |
| MLA | Yang, Tao,et al."Na-8[Cr4B12P8O44(OH)(4)][P2O7]center dot nH(2)O: A 3D borophosphate framework with spherical cages".CHEMISTRY-A EUROPEAN JOURNAL 14.24(2008):7212-7217. |
入库方式： OAI收割
来源：化学研究所
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