Tridentate N(boolean AND)N(boolean AND)N iron(II) and cobalt(II) complexes of ion-paired structures: Synthesis, characterization and magnetism
文献类型:期刊论文
作者 | Wang, Kefeng1,2; Hao, Peng1,2; Zhang, Deqing2,3; Sun, Wen-Hua1,2![]() |
刊名 | JOURNAL OF MOLECULAR STRUCTURE
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出版日期 | 2008-11-12 |
卷号 | 890期号:1-3页码:95-100 |
关键词 | Iron And Cobalt Complex Tridentate n(Boolean And)n(Boolean And)n Complex Magnetism |
ISSN号 | 0022-2860 |
DOI | 10.1016/j.molstruc.2008.03.027 |
英文摘要 | Two kinds of ion-paired iron and cobalt complexes ligated by 2-(benzimidazolyl)-6-(1-(arylimino)ethyl)pyridyl [iron (1a) and cobalt (1b)] or N-(pyridin-2-yl)methylene)-quinolin-8-amine (iron, 2a) were synthesized and well characterized by IR, EA and X-ray diffraction analysis. They were confirmed to be in the form of [ML(2)](2+)[MCl(4)](2-) or [ML(2)](2+)2[MCl(4)](1-) and the cations took octahedral coordinated geometry. Structure research indicated that complex 1a was in low-spin state while complex 1b was in high-spin state. Furthermore, their magnetic susceptibility measurements were performed and the complexes showed interesting magnetic properties. (C) 2008 Elsevier B.V. All rights reserved. |
语种 | 英语 |
WOS记录号 | WOS:000261121100015 |
出版者 | ELSEVIER SCIENCE BV |
源URL | [http://ir.iccas.ac.cn/handle/121111/65641] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Sun, Wen-Hua |
作者单位 | 1.Chinese Acad Sci, Inst Chem, Key Lab Engn Plast, Beijing 100080, Peoples R China 2.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100080, Peoples R China 3.Chinese Acad Sci, Inst Chem, Key Lab Organ Solids, Beijing 100080, Peoples R China |
推荐引用方式 GB/T 7714 | Wang, Kefeng,Hao, Peng,Zhang, Deqing,et al. Tridentate N(boolean AND)N(boolean AND)N iron(II) and cobalt(II) complexes of ion-paired structures: Synthesis, characterization and magnetism[J]. JOURNAL OF MOLECULAR STRUCTURE,2008,890(1-3):95-100. |
APA | Wang, Kefeng,Hao, Peng,Zhang, Deqing,&Sun, Wen-Hua.(2008).Tridentate N(boolean AND)N(boolean AND)N iron(II) and cobalt(II) complexes of ion-paired structures: Synthesis, characterization and magnetism.JOURNAL OF MOLECULAR STRUCTURE,890(1-3),95-100. |
MLA | Wang, Kefeng,et al."Tridentate N(boolean AND)N(boolean AND)N iron(II) and cobalt(II) complexes of ion-paired structures: Synthesis, characterization and magnetism".JOURNAL OF MOLECULAR STRUCTURE 890.1-3(2008):95-100. |
入库方式: OAI收割
来源:化学研究所
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