Transformation of 2-alkoxyimidate-1,10-phenanthroline) metal (Mn2+, Co2+ and Ni2+) chlorides from bis(2-cyano-1,10-phenanthroline) metal chlorides: Syntheses, characterizations and their catalytic behavior toward ethylene oligomerization
文献类型：期刊论文
| 作者 | Xiao, Liwei2; Jie, Suyun1; Song, Yingxia1; Cao, Xiaoping2; Sun, Wen-Hua1,2
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| 刊名 | JOURNAL OF ORGANOMETALLIC CHEMISTRY
 |
| 出版日期 | 2008-12-15 |
| 卷号 | 693期号:26页码:3858-3866 |
| 关键词 | Manganese Cobalt Nickel Ethylene Oligomerization 2-alkoxyimidate-1 2-cyano-1 10-phenanthroline 10-phenanthroline |
| ISSN号 | 0022-328X |
| DOI | 10.1016/j.jorganchem.2008.09.052 |
| 英文摘要 | The 2-alkoxyimidate-1,10-phenanthroline complexes of manganese, cobalt and nickel have been synthesized by the reaction of 2-cyano-1,10-phenanthroline with metal dichloride in the corresponding alcohol. The metal complexes bearing two 2-cyano- 1,10-phenanthrolines were isolated in non-protonic solvent as the coordination around metal core with two ligands and two chlorides. The alkoxyimidation of nitrile linked on ligand was speeded in forming the 2-alkoxyimidate-1,10-phenanthrolinyl metal complexes. All the complexes have been characterized by FT-IR spectra and elemental analysis, and some of their structures have also been confirmed by single-crystal X-ray diffraction analysis. All the metal complexes were evaluated in the catalytic oligomerization of ethylene with some alkylaluminums as co-catalyst; in which manganese complexes were less active, cobalt complexes showed low to moderate activities, and nickel complexes gave moderate to good activities. (C) 2008 Elsevier B.V. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000261162900011 |
| 出版者 | ELSEVIER SCIENCE SA |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/65655]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Sun, Wen-Hua |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Key Lab Engn Plast, Beijing 100190, Peoples R China 2.Lanzhou Univ, Coll Chem & Chem Engn, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xiao, Liwei,Jie, Suyun,Song, Yingxia,et al. Transformation of 2-alkoxyimidate-1,10-phenanthroline) metal (Mn2+, Co2+ and Ni2+) chlorides from bis(2-cyano-1,10-phenanthroline) metal chlorides: Syntheses, characterizations and their catalytic behavior toward ethylene oligomerization[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY,2008,693(26):3858-3866. |
| APA | Xiao, Liwei,Jie, Suyun,Song, Yingxia,Cao, Xiaoping,&Sun, Wen-Hua.(2008).Transformation of 2-alkoxyimidate-1,10-phenanthroline) metal (Mn2+, Co2+ and Ni2+) chlorides from bis(2-cyano-1,10-phenanthroline) metal chlorides: Syntheses, characterizations and their catalytic behavior toward ethylene oligomerization.JOURNAL OF ORGANOMETALLIC CHEMISTRY,693(26),3858-3866. |
| MLA | Xiao, Liwei,et al."Transformation of 2-alkoxyimidate-1,10-phenanthroline) metal (Mn2+, Co2+ and Ni2+) chlorides from bis(2-cyano-1,10-phenanthroline) metal chlorides: Syntheses, characterizations and their catalytic behavior toward ethylene oligomerization".JOURNAL OF ORGANOMETALLIC CHEMISTRY 693.26(2008):3858-3866. |
入库方式： OAI收割
来源：化学研究所
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