Epoxidation of styrene to styrene oxide using carbon dioxide and hydrogen peroxide in ionic liquids
文献类型：期刊论文
| 作者 | Song, Jinliang; Zhang, Zhaofu; Jiang, Tao; Hu, Suqin; Li, Wenjing; Xie, Ye; Han, Buxing |
| 刊名 | JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
 |
| 出版日期 | 2008-01-18 |
| 卷号 | 279期号:2页码:235-238 |
| 关键词 | Epoxidation Styrene Hydrogen Peroxide Compressed Carbon Dioxide Ionic Liquids |
| ISSN号 | 1381-1169 |
| DOI | 10.1016/j.molcata.2007.02.001 |
| 英文摘要 | The epoxidation of styrene using hydrogen peroxide and compressed CO2 was conducted in 1-butyl-3-methylimidazolium tetrafluoroborate ([bmim][BF4]), 1-butyl-3-methylimidazolium hexafluoroborate ([bmim][PF6]), 1-butyl-3-methylimidazolium chloride ([bmim]Cl), 1,1,3,3-tetramethylguanidinium lactate [TMG][Lac], 1,1,3,3-tetramethylguanidinium trifluoroacetate [TMG][CF3COO], ethanol, and acetonitrile. It was demonstrated that the reaction could be carried out effectively in [bmim][BF4] or [bmim]Cl without any metallic catalysts. HCO4- produced from CO2 and H2O2 acted as the catalyst. The conversion of styrene and the yield of styrene oxide could reach 95% and 69%, respectively. (c) 2007 Elsevier B.V. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000252803300015 |
| 出版者 | ELSEVIER SCIENCE BV |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/65741]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Han, Buxing |
| 作者单位 | Chinese Acad Sci, Beijing Natl Lab Mol Sci, Inst Chem, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Song, Jinliang,Zhang, Zhaofu,Jiang, Tao,et al. Epoxidation of styrene to styrene oxide using carbon dioxide and hydrogen peroxide in ionic liquids[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL,2008,279(2):235-238. |
| APA | Song, Jinliang.,Zhang, Zhaofu.,Jiang, Tao.,Hu, Suqin.,Li, Wenjing.,...&Han, Buxing.(2008).Epoxidation of styrene to styrene oxide using carbon dioxide and hydrogen peroxide in ionic liquids.JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL,279(2),235-238. |
| MLA | Song, Jinliang,et al."Epoxidation of styrene to styrene oxide using carbon dioxide and hydrogen peroxide in ionic liquids".JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL 279.2(2008):235-238. |
入库方式： OAI收割
来源：化学研究所
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