中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Epoxidation of styrene to styrene oxide using carbon dioxide and hydrogen peroxide in ionic liquids

文献类型:期刊论文

作者Song, Jinliang; Zhang, Zhaofu; Jiang, Tao; Hu, Suqin; Li, Wenjing; Xie, Ye; Han, Buxing
刊名JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
出版日期2008-01-18
卷号279期号:2页码:235-238
关键词Epoxidation Styrene Hydrogen Peroxide Compressed Carbon Dioxide Ionic Liquids
ISSN号1381-1169
DOI10.1016/j.molcata.2007.02.001
英文摘要The epoxidation of styrene using hydrogen peroxide and compressed CO2 was conducted in 1-butyl-3-methylimidazolium tetrafluoroborate ([bmim][BF4]), 1-butyl-3-methylimidazolium hexafluoroborate ([bmim][PF6]), 1-butyl-3-methylimidazolium chloride ([bmim]Cl), 1,1,3,3-tetramethylguanidinium lactate [TMG][Lac], 1,1,3,3-tetramethylguanidinium trifluoroacetate [TMG][CF3COO], ethanol, and acetonitrile. It was demonstrated that the reaction could be carried out effectively in [bmim][BF4] or [bmim]Cl without any metallic catalysts. HCO4- produced from CO2 and H2O2 acted as the catalyst. The conversion of styrene and the yield of styrene oxide could reach 95% and 69%, respectively. (c) 2007 Elsevier B.V. All rights reserved.
语种英语
WOS记录号WOS:000252803300015
出版者ELSEVIER SCIENCE BV
源URL[http://ir.iccas.ac.cn/handle/121111/65741]  
专题中国科学院化学研究所
通讯作者Han, Buxing
作者单位Chinese Acad Sci, Beijing Natl Lab Mol Sci, Inst Chem, Beijing 100080, Peoples R China
推荐引用方式
GB/T 7714
Song, Jinliang,Zhang, Zhaofu,Jiang, Tao,et al. Epoxidation of styrene to styrene oxide using carbon dioxide and hydrogen peroxide in ionic liquids[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL,2008,279(2):235-238.
APA Song, Jinliang.,Zhang, Zhaofu.,Jiang, Tao.,Hu, Suqin.,Li, Wenjing.,...&Han, Buxing.(2008).Epoxidation of styrene to styrene oxide using carbon dioxide and hydrogen peroxide in ionic liquids.JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL,279(2),235-238.
MLA Song, Jinliang,et al."Epoxidation of styrene to styrene oxide using carbon dioxide and hydrogen peroxide in ionic liquids".JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL 279.2(2008):235-238.

入库方式: OAI收割

来源:化学研究所

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