Electrochromism based on the charge transfer process in a ferrocene-BODIPY molecule
文献类型：期刊论文
| 作者 | Yin, Xiaodong1; Li, Yongjun1; Li, Yuliang1; Zhu, Yulan3; Tang, Xueling3; Zheng, Haiyan1,2; Zhu, Daoben1 |
| 刊名 | TETRAHEDRON
 |
| 出版日期 | 2009-10-03 |
| 卷号 | 65期号:40页码:8373-8377 |
| 关键词 | Electrochromism Organic Metallic Compound Density Functional Theoretical Calculation Charge Transfer |
| ISSN号 | 0040-4020 |
| DOI | 10.1016/j.tet.2009.08.008 |
| 英文摘要 | A new type of donor-acceptor molecule DiFc-B combined ferrocene and BODIPY unit has been synthesized, and the NMR spectra, photophysical property, and electrochemical property were studied. The in situ spectro-electrochemical experiment was carried out, a notable absorption change had been observed under oxidative potential, and a recovery could happen under reductive potential and this process could repeat for several times. Such a phenomenon also happened when oxidative metal ion was added into the solution of DiFc-B. In order to study the mechanism of the electrochromism, the theoretical calculation was performed, and the result shows a D (ferrocene)-pi-A (BODIPY) system. The energy gap between the HOMO and LUMO had a good consistence with the electrochemical experiment and UV-vis data. The calculation of the frontier orbital belonging to the cation state of Difc-B shows the directional change of the D-pi-A system, which supplied a theoretical basis of the electrochromism. Crown Copyright (C) 2009 Published by Elsevier Ltd. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000269995900009 |
| 出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/65785]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Li, Yuliang |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, BNLMS,CAS Key Lab Organ Solids, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100190, Peoples R China 3.Huaiyin Teachers Coll, Jiangsu Key Lab Chem Low Dimens Mat, Huaian 223300, Jiangsu, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yin, Xiaodong,Li, Yongjun,Li, Yuliang,et al. Electrochromism based on the charge transfer process in a ferrocene-BODIPY molecule[J]. TETRAHEDRON,2009,65(40):8373-8377. |
| APA | Yin, Xiaodong.,Li, Yongjun.,Li, Yuliang.,Zhu, Yulan.,Tang, Xueling.,...&Zhu, Daoben.(2009).Electrochromism based on the charge transfer process in a ferrocene-BODIPY molecule.TETRAHEDRON,65(40),8373-8377. |
| MLA | Yin, Xiaodong,et al."Electrochromism based on the charge transfer process in a ferrocene-BODIPY molecule".TETRAHEDRON 65.40(2009):8373-8377. |
入库方式： OAI收割
来源：化学研究所
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