Glycine-glutamic-acid-based organogelators and their fluoride anion responsive properties
文献类型：期刊论文
| 作者 | Teng, Mingjun1; Kuang, Guichao1; Jia, Xinru1; Gao, Min1; Li, Yan1; Wei, Yen2 |
| 刊名 | JOURNAL OF MATERIALS CHEMISTRY
 |
| 出版日期 | 2009 |
| 卷号 | 19期号:31页码:5648-5654 |
| ISSN号 | 0959-9428 |
| DOI | 10.1039/b904263f |
| 英文摘要 | Novel low-molecular-weight organogelators (LMOGs) 1 and 2 derived from glycine-glutamic-acids (GGA) based dipeptide were synthesized. The difference on the chemical structures between 1 and 2 resulted in some interesting variations on their gelling behavior and fluoride anion (F(-)) responsive properties. Gelator 1 could gel aromatic solvents effectively, while gelator 2 possessed excellent gelation ability in protic solvents. Upon the addition of 0.5 equiv. F(-), the toluene gel of 1 transformed into solution due to the disruption of the intermolecular hydrogen-bonding, whereas the alcohol gel of 2 was stable and preserved even by introducing 20 equiv. F(-). Interestingly, 2 could be regarded as an efficient receptor for F(-) in acetonitrile (MeCN) solution. After the addition of F(-), the fluorescent emission band of 2 red-shifted from 360 to 420 nm with the emission intensity enhanced drastically; the intensity of the CD signal decreased and almost disappeared after addition of 2 equiv. F(-). These changes were due to the conformational change and hydrogen-bonding interaction between urea groups and F(-). The results indicated that GGA-based 1 and 2 might represent potential sensor materials for the naked-eye detection of F(-). |
| 语种 | 英语 |
| WOS记录号 | WOS:000268439300024 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/65789]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Jia, Xinru |
| 作者单位 | 1.Peking Univ, Beijing Natl Lab Mol Sci, Key Lab Polymer Chem & Phys, Minist Educ,Coll Chem & Mol Engn, Beijing 100871, Peoples R China 2.Drexel Univ, Dept Chem, Philadelphia, PA 19104 USA |
| 推荐引用方式 GB/T 7714 | Teng, Mingjun,Kuang, Guichao,Jia, Xinru,et al. Glycine-glutamic-acid-based organogelators and their fluoride anion responsive properties[J]. JOURNAL OF MATERIALS CHEMISTRY,2009,19(31):5648-5654. |
| APA | Teng, Mingjun,Kuang, Guichao,Jia, Xinru,Gao, Min,Li, Yan,&Wei, Yen.(2009).Glycine-glutamic-acid-based organogelators and their fluoride anion responsive properties.JOURNAL OF MATERIALS CHEMISTRY,19(31),5648-5654. |
| MLA | Teng, Mingjun,et al."Glycine-glutamic-acid-based organogelators and their fluoride anion responsive properties".JOURNAL OF MATERIALS CHEMISTRY 19.31(2009):5648-5654. |
入库方式： OAI收割
来源：化学研究所
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