Synthesis, surface and aggregation properties of a series of amphiphilic dendritic copolymers
文献类型:期刊论文
作者 | Zhang, Wei1,2; Dong, Guojun1; Yang, Hui1,2; Sun, Jinhong1,2; Zhou, Jizhu2; Wang, Jinben2 |
刊名 | COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
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出版日期 | 2009-09-20 |
卷号 | 348期号:1-3页码:45-48 |
关键词 | Dendrimer Copolymer Cmc Cloud Point Aggregation Behavior |
ISSN号 | 0927-7757 |
DOI | 10.1016/j.colsurfa.2009.06.029 |
英文摘要 | With 3.0 G polyamidoamine (PAMAM) as initiator and poly (propylene oxide) (PPO)-poly (ethylene oxide) (PEO) blocks as branches, a new class of amphiphilic copolymers were synthesized. The critical micelle concentration (CMC) and gamma(CMC) (Surface tension at CIVIC) values were determined by Surface tension measurement, and the result showed that they both decrease with the increase of amphiphilic branch length. The turbidity properties were investigated and it was found that the cloud point (CP) temperature decreases as the PEO block length increases. Freeze-fracture transmission electron microscopy (FF-TEM) results exhibited spherical shape of aggregates with the most probable distribution size of around 100 nm, which agrees with the results of the dynamic light scattering (DLS). Moreover, the relationship between PPO block length and the activity and CP properties was discussed. (C) 2009 Elsevier B.V. All rights reserved. |
语种 | 英语 |
WOS记录号 | WOS:000270623900008 |
出版者 | ELSEVIER SCIENCE BV |
源URL | [http://ir.iccas.ac.cn/handle/121111/65871] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Dong, Guojun |
作者单位 | 1.Harbin Engn Univ, Coll Mat Sci & Chem Engn, Harbin 150001, Peoples R China 2.Chinese Acad Sci, Inst Chem, Key Lab Colloid Interface & Chem Thermodynam, Beijing 100190, Peoples R China |
推荐引用方式 GB/T 7714 | Zhang, Wei,Dong, Guojun,Yang, Hui,et al. Synthesis, surface and aggregation properties of a series of amphiphilic dendritic copolymers[J]. COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS,2009,348(1-3):45-48. |
APA | Zhang, Wei,Dong, Guojun,Yang, Hui,Sun, Jinhong,Zhou, Jizhu,&Wang, Jinben.(2009).Synthesis, surface and aggregation properties of a series of amphiphilic dendritic copolymers.COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS,348(1-3),45-48. |
MLA | Zhang, Wei,et al."Synthesis, surface and aggregation properties of a series of amphiphilic dendritic copolymers".COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS 348.1-3(2009):45-48. |
入库方式: OAI收割
来源:化学研究所
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