中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Synthesis, surface and aggregation properties of a series of amphiphilic dendritic copolymers

文献类型:期刊论文

作者Zhang, Wei1,2; Dong, Guojun1; Yang, Hui1,2; Sun, Jinhong1,2; Zhou, Jizhu2; Wang, Jinben2
刊名COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
出版日期2009-09-20
卷号348期号:1-3页码:45-48
关键词Dendrimer Copolymer Cmc Cloud Point Aggregation Behavior
ISSN号0927-7757
DOI10.1016/j.colsurfa.2009.06.029
英文摘要With 3.0 G polyamidoamine (PAMAM) as initiator and poly (propylene oxide) (PPO)-poly (ethylene oxide) (PEO) blocks as branches, a new class of amphiphilic copolymers were synthesized. The critical micelle concentration (CMC) and gamma(CMC) (Surface tension at CIVIC) values were determined by Surface tension measurement, and the result showed that they both decrease with the increase of amphiphilic branch length. The turbidity properties were investigated and it was found that the cloud point (CP) temperature decreases as the PEO block length increases. Freeze-fracture transmission electron microscopy (FF-TEM) results exhibited spherical shape of aggregates with the most probable distribution size of around 100 nm, which agrees with the results of the dynamic light scattering (DLS). Moreover, the relationship between PPO block length and the activity and CP properties was discussed. (C) 2009 Elsevier B.V. All rights reserved.
语种英语
WOS记录号WOS:000270623900008
出版者ELSEVIER SCIENCE BV
源URL[http://ir.iccas.ac.cn/handle/121111/65871]  
专题中国科学院化学研究所
通讯作者Dong, Guojun
作者单位1.Harbin Engn Univ, Coll Mat Sci & Chem Engn, Harbin 150001, Peoples R China
2.Chinese Acad Sci, Inst Chem, Key Lab Colloid Interface & Chem Thermodynam, Beijing 100190, Peoples R China
推荐引用方式
GB/T 7714
Zhang, Wei,Dong, Guojun,Yang, Hui,et al. Synthesis, surface and aggregation properties of a series of amphiphilic dendritic copolymers[J]. COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS,2009,348(1-3):45-48.
APA Zhang, Wei,Dong, Guojun,Yang, Hui,Sun, Jinhong,Zhou, Jizhu,&Wang, Jinben.(2009).Synthesis, surface and aggregation properties of a series of amphiphilic dendritic copolymers.COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS,348(1-3),45-48.
MLA Zhang, Wei,et al."Synthesis, surface and aggregation properties of a series of amphiphilic dendritic copolymers".COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS 348.1-3(2009):45-48.

入库方式: OAI收割

来源:化学研究所

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