中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
A facile route to design pH-responsive viscoelastic wormlike micelles: Smart use of hydrotropes

文献类型:期刊论文

作者Lin, Yiyang1; Han, Xue1; Huang, Jianbin1; Fu, Honglan2; Yu, Cailan3
刊名JOURNAL OF COLLOID AND INTERFACE SCIENCE
出版日期2009-02-15
卷号330期号:2页码:449-455
关键词Ph Responsive Wormlike Micelle Viscoelastic Fluid Hydrotrope
ISSN号0021-9797
DOI10.1016/j.jcis.2008.10.071
英文摘要A simple and effective route to design pH-responsive viscoelastic wormlike micelles based on commercial compounds is reported. According to this route, pH-sensitive viscoelastic fluids can be easily obtained by introducing a pH-responsive hydrotrope into a surfactant solution. In this paper, the mixed system of cetyltrimethylammonium bromide (CTAB) and potassium phthalic acid (PPA) was studied in detail. This pH-sensitive fluid can be switched between a gellike state and a waterlike state within a narrow pH change. Rheology and DLS results revealed that the pH-sensitive flowing behavior was attributed to the microstructure transition between wormlike micelles and short cylindrical micelles. Combined with fluorescence anisotropy, NMR, and UV-vis, it was demonstrated that the pH response of viscoelastic fluid originated from the different binding abilities of hydrotrope to surfactant as pH varies. Furthermore, different kinds of hydrotropes can be utilized to prepare pH-responsive viscoelastic fluids in the desired pH areas. (C) 2008 Elsevier Inc. All rights reserved.
语种英语
WOS记录号WOS:000262760600029
出版者ACADEMIC PRESS INC ELSEVIER SCIENCE
源URL[http://ir.iccas.ac.cn/handle/121111/65879]  
专题中国科学院化学研究所
通讯作者Huang, Jianbin
作者单位1.Peking Univ, BNLMS, State Key Lab Struct Chem Unstable & Stable Speci, Coll Chem & Mol Engn, Beijing 100871, Peoples R China
2.Peking Univ, Coll Life Sci, Beijing 100871, Peoples R China
3.Chinese Acad Sci, Inst Chem, CAS Key Lab Photochem, Beijing 100080, Peoples R China
推荐引用方式
GB/T 7714
Lin, Yiyang,Han, Xue,Huang, Jianbin,et al. A facile route to design pH-responsive viscoelastic wormlike micelles: Smart use of hydrotropes[J]. JOURNAL OF COLLOID AND INTERFACE SCIENCE,2009,330(2):449-455.
APA Lin, Yiyang,Han, Xue,Huang, Jianbin,Fu, Honglan,&Yu, Cailan.(2009).A facile route to design pH-responsive viscoelastic wormlike micelles: Smart use of hydrotropes.JOURNAL OF COLLOID AND INTERFACE SCIENCE,330(2),449-455.
MLA Lin, Yiyang,et al."A facile route to design pH-responsive viscoelastic wormlike micelles: Smart use of hydrotropes".JOURNAL OF COLLOID AND INTERFACE SCIENCE 330.2(2009):449-455.

入库方式: OAI收割

来源:化学研究所

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