A facile route to design pH-responsive viscoelastic wormlike micelles: Smart use of hydrotropes
文献类型:期刊论文
作者 | Lin, Yiyang1; Han, Xue1; Huang, Jianbin1; Fu, Honglan2; Yu, Cailan3 |
刊名 | JOURNAL OF COLLOID AND INTERFACE SCIENCE
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出版日期 | 2009-02-15 |
卷号 | 330期号:2页码:449-455 |
关键词 | Ph Responsive Wormlike Micelle Viscoelastic Fluid Hydrotrope |
ISSN号 | 0021-9797 |
DOI | 10.1016/j.jcis.2008.10.071 |
英文摘要 | A simple and effective route to design pH-responsive viscoelastic wormlike micelles based on commercial compounds is reported. According to this route, pH-sensitive viscoelastic fluids can be easily obtained by introducing a pH-responsive hydrotrope into a surfactant solution. In this paper, the mixed system of cetyltrimethylammonium bromide (CTAB) and potassium phthalic acid (PPA) was studied in detail. This pH-sensitive fluid can be switched between a gellike state and a waterlike state within a narrow pH change. Rheology and DLS results revealed that the pH-sensitive flowing behavior was attributed to the microstructure transition between wormlike micelles and short cylindrical micelles. Combined with fluorescence anisotropy, NMR, and UV-vis, it was demonstrated that the pH response of viscoelastic fluid originated from the different binding abilities of hydrotrope to surfactant as pH varies. Furthermore, different kinds of hydrotropes can be utilized to prepare pH-responsive viscoelastic fluids in the desired pH areas. (C) 2008 Elsevier Inc. All rights reserved. |
语种 | 英语 |
WOS记录号 | WOS:000262760600029 |
出版者 | ACADEMIC PRESS INC ELSEVIER SCIENCE |
源URL | [http://ir.iccas.ac.cn/handle/121111/65879] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Huang, Jianbin |
作者单位 | 1.Peking Univ, BNLMS, State Key Lab Struct Chem Unstable & Stable Speci, Coll Chem & Mol Engn, Beijing 100871, Peoples R China 2.Peking Univ, Coll Life Sci, Beijing 100871, Peoples R China 3.Chinese Acad Sci, Inst Chem, CAS Key Lab Photochem, Beijing 100080, Peoples R China |
推荐引用方式 GB/T 7714 | Lin, Yiyang,Han, Xue,Huang, Jianbin,et al. A facile route to design pH-responsive viscoelastic wormlike micelles: Smart use of hydrotropes[J]. JOURNAL OF COLLOID AND INTERFACE SCIENCE,2009,330(2):449-455. |
APA | Lin, Yiyang,Han, Xue,Huang, Jianbin,Fu, Honglan,&Yu, Cailan.(2009).A facile route to design pH-responsive viscoelastic wormlike micelles: Smart use of hydrotropes.JOURNAL OF COLLOID AND INTERFACE SCIENCE,330(2),449-455. |
MLA | Lin, Yiyang,et al."A facile route to design pH-responsive viscoelastic wormlike micelles: Smart use of hydrotropes".JOURNAL OF COLLOID AND INTERFACE SCIENCE 330.2(2009):449-455. |
入库方式: OAI收割
来源:化学研究所
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