Structure and Properties of New Thermoforming Bionanocomposites Based on Chitin Whisker-Graft-Polycaprolactone
文献类型：期刊论文
| 作者 | Feng, Liangdong1; Zhou, Ziyan2; Dufresne, Alain3; Huang, Jin2,3; Wei, Ming2; An, Lijia4 |
| 刊名 | JOURNAL OF APPLIED POLYMER SCIENCE
 |
| 出版日期 | 2009-06-05 |
| 卷号 | 112期号:5页码:2830-2837 |
| 关键词 | Chitin Whisker Bionanocomposite Graft Thermoforming Mechanical Properties |
| ISSN号 | 0021-8995 |
| DOI | 10.1002/app.29731 |
| 英文摘要 | Thermoformable bionanocomposites of chitin whisker-graft-polycaprolactone (CHW-g-PCL) were synthesized by initiating the ring-opening polymerization of caprolactone monomer onto the CHW surface under microwave radiation. In this case, the "graft from" strategy contributed to long and dense "plasticizing" PCL tails onto the CHW surface as the key of thermoforming, and, therefore, Such bionanocomposites were injection-molded as the sheets with a Structure of cocontinuous phase mediated with the entanglement of grafted PCL chains. The structure and properties of the molded CHW-g-PCL sheets were investigated by FTIR, XRD, SEM, DSC, DMTA, contact angle measurement, and tensile test. With an increase of the PCL content in CHW-g-PCL, the strength and elongation as well as the hydrophobicity of the nanocomposites increased at one time. This is the first report on the thermoformable polymer-grafted nanocrystal derived from natural polysaccharide. Moreover, such new bionanocomposites with good mechanical performances could have great potential applications. (C) 2009 Wiley Periodicals, Inc. J Appl Polym Sci 112: 28302837, 2009 |
| 语种 | 英语 |
| WOS记录号 | WOS:000265076100029 |
| 出版者 | WILEY-BLACKWELL |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/65915]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Feng, Liangdong |
| 作者单位 | 1.Huaiyin Inst Technol, Dept Chem Engn, Key Lab Attapulgite Sci & Appl Technol Jiangsu Pr, Huaian 223003, Peoples R China 2.Wuhan Univ Technol, Coll Chem Engn, Wuhan 430070, Peoples R China 3.Ecole Francaise Papeterie & Ind Graph, Inst Natl Polytech Grenoble, F-38402 St Martin Dheres, France 4.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China |
| 推荐引用方式 GB/T 7714 | Feng, Liangdong,Zhou, Ziyan,Dufresne, Alain,et al. Structure and Properties of New Thermoforming Bionanocomposites Based on Chitin Whisker-Graft-Polycaprolactone[J]. JOURNAL OF APPLIED POLYMER SCIENCE,2009,112(5):2830-2837. |
| APA | Feng, Liangdong,Zhou, Ziyan,Dufresne, Alain,Huang, Jin,Wei, Ming,&An, Lijia.(2009).Structure and Properties of New Thermoforming Bionanocomposites Based on Chitin Whisker-Graft-Polycaprolactone.JOURNAL OF APPLIED POLYMER SCIENCE,112(5),2830-2837. |
| MLA | Feng, Liangdong,et al."Structure and Properties of New Thermoforming Bionanocomposites Based on Chitin Whisker-Graft-Polycaprolactone".JOURNAL OF APPLIED POLYMER SCIENCE 112.5(2009):2830-2837. |
入库方式： OAI收割
来源：化学研究所
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