Building thiol and metal-thiolate functions into coordination nets: Clues from a simple molecule
文献类型：期刊论文
| 作者 | He, Jun1; Yang, Chen1; Xu, Zhengtao1; Zeller, Matthias2; Hunter, Allen D.2; Lin, Jianhua3 |
| 刊名 | JOURNAL OF SOLID STATE CHEMISTRY
 |
| 出版日期 | 2009-07-01 |
| 卷号 | 182期号:7页码:1821-1826 |
| 关键词 | Metal-thiolate Networks Coordination Networks Bifunctional Ligands Crystal Engineering |
| ISSN号 | 0022-4596 |
| DOI | 10.1016/j.jssc.2009.04.024 |
| 英文摘要 | The simple and easy-to-prepare bifunctional molecule 2,5-dimercapto-1,4-benzenedicarboxylic acid (H(4)DMBD) interacts with the increasingly harder metal ions of Cu(+), Pb(2+) and Eu(3+) to form the coordination networks Of Cu(6)(DMBD)(3)(en)(4)(Hen)(6), (1), Pb(2)(DMBD)(en)(2) (2) and Eu(2)(H(2)DMBD)(3)(DEF)(4) (3), where the carboxyl and thiol groups bind with distinct preference to the hard and soft metal ions, respectively. Notably, 1 features uncoordinated carboxylate groups and Cu(3) cluster units integrated via the thiolate groups into an extended network with significant interaction between the metal centers and the organic molecules; 2 features a 2D coordination net based On the mercapto and carboxylic groups all bonded to the Pb(2+) ions; 3 features free-standing thiol groups inside the channels of a metal-carboxylate-based network. This study illustrates the rich solid state structural features and potential functions offered by the carboxyl-thiol combination. (C) 2009 Elsevier Inc. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000267717600032 |
| 出版者 | ACADEMIC PRESS INC ELSEVIER SCIENCE |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/65925]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Xu, Zhengtao |
| 作者单位 | 1.City Univ Hong Kong, Dept Biol & Chem, Kowloon, Hong Kong, Peoples R China 2.Youngstown State Univ, Dept Chem, Youngstown, OH 44555 USA 3.Peking Univ, Beijing Natl Lab Mol Sci, State Key Lab Rare Earth Mat Chem & Applicat, Coll Chem & Mol Engn, Beijing 100871, Peoples R China |
| 推荐引用方式 GB/T 7714 | He, Jun,Yang, Chen,Xu, Zhengtao,et al. Building thiol and metal-thiolate functions into coordination nets: Clues from a simple molecule[J]. JOURNAL OF SOLID STATE CHEMISTRY,2009,182(7):1821-1826. |
| APA | He, Jun,Yang, Chen,Xu, Zhengtao,Zeller, Matthias,Hunter, Allen D.,&Lin, Jianhua.(2009).Building thiol and metal-thiolate functions into coordination nets: Clues from a simple molecule.JOURNAL OF SOLID STATE CHEMISTRY,182(7),1821-1826. |
| MLA | He, Jun,et al."Building thiol and metal-thiolate functions into coordination nets: Clues from a simple molecule".JOURNAL OF SOLID STATE CHEMISTRY 182.7(2009):1821-1826. |
入库方式： OAI收割
来源：化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。