New double formates Na3M(HCOO)(6) (M = Ga, In) with diamond-like metal framework: Synthesis, structure and coordination modes
文献类型：期刊论文
| 作者 | Su, Jie; Wang, Yingxia; Li, Weihong; Yang, Sihai; Li, Guobao; Liao, Fuhui; Lin, Jianhua |
| 刊名 | JOURNAL OF MOLECULAR STRUCTURE
 |
| 出版日期 | 2009-11-26 |
| 卷号 | 937期号:1-3页码:39-43 |
| 关键词 | Gallium Formate Indium Formate Sodium Formate Double Formates X-ray Crystal Structure |
| ISSN号 | 0022-2860 |
| DOI | 10.1016/j.molstruc.2009.08.009 |
| 英文摘要 | Two new double formates, Na3M(HCOO)(6) (M = Ga, In), have been synthesized by using quasi-solvothermal method. Both Compounds are iscistructural, crystallizing in orthorhombic space group Pccn, with lattice parameters a = 14.6279(5) angstrom, b = 6.2607(1) angstrom, and c = 13.5132(4) angstrom for Na3Ga(HCOO)(6) and a = 14.6054(5) angstrom, b = 6.4160(1) angstrom, and c = 13.9444(3) angstrom for Na3In(HCOO)(6). The structure takes a three-dimensional framework consisting of MO6 and NaO6 octahedra which are connected in edge- and corner-sharing modes. Regarding to the linkage of octahedra, the framework could be considered as a diamond net. The formates in the structure bridge the metal octahedra in an unusual 4.22 connection mode. IR spectroscopy and elemental analysis support the Structure characterization. Thermal decomposition process was also studied by TG and X-ray diffraction. (C) 2009 Elsevier B.V. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000271838100006 |
| 出版者 | ELSEVIER SCIENCE BV |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/65963]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Wang, Yingxia |
| 作者单位 | Peking Univ, Beijing Natl Lab Mol Sci, State Key Lab Rare Earth Mat Chem & Applicat, Coll Chem & Mol Engn, Beijing 100871, Peoples R China |
| 推荐引用方式 GB/T 7714 | Su, Jie,Wang, Yingxia,Li, Weihong,et al. New double formates Na3M(HCOO)(6) (M = Ga, In) with diamond-like metal framework: Synthesis, structure and coordination modes[J]. JOURNAL OF MOLECULAR STRUCTURE,2009,937(1-3):39-43. |
| APA | Su, Jie.,Wang, Yingxia.,Li, Weihong.,Yang, Sihai.,Li, Guobao.,...&Lin, Jianhua.(2009).New double formates Na3M(HCOO)(6) (M = Ga, In) with diamond-like metal framework: Synthesis, structure and coordination modes.JOURNAL OF MOLECULAR STRUCTURE,937(1-3),39-43. |
| MLA | Su, Jie,et al."New double formates Na3M(HCOO)(6) (M = Ga, In) with diamond-like metal framework: Synthesis, structure and coordination modes".JOURNAL OF MOLECULAR STRUCTURE 937.1-3(2009):39-43. |
入库方式： OAI收割
来源：化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。