Spectroscopic evidence for the specific Na+ and K+ interactions with the hydrogen-bonded water molecules at the electrolyte aqueous solution surfaces
文献类型：期刊论文
| 作者 | Feng, Ran-ran1,2; Bian, Hong-tao1,2; Guo, Yuan1; Wang, Hong-fei1 |
| 刊名 | JOURNAL OF CHEMICAL PHYSICS
 |
| 出版日期 | 2009-04-07 |
| 卷号 | 130期号:13 |
| 关键词 | Electrolytes Hydrogen Bonds Interface Phenomena Ion-molecule Collisions Positive Ions Potassium Sodium Vibrational States Water |
| ISSN号 | 0021-9606 |
| DOI | 10.1063/1.3104610 |
| 英文摘要 | Sum frequency generation vibrational spectra of the water molecules at the NaF and KF aqueous solution surfaces showed significantly different spectral features and different concentration dependence. This result is the first direct observation of the cation effects of the simple alkali cations, which have been believed to be depleted from the aqueous surface, on the hydrogen bonding structure of the water molecules at the electrolyte solution surfaces. These observations may provide important clues to understand the fundamental phenomenon of ions at the air/water interface. |
| 语种 | 英语 |
| WOS记录号 | WOS:000265053200058 |
| 出版者 | AMER INST PHYSICS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/65969]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Wang, Hong-fei |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, State Key Lab Mol React Dynam, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Feng, Ran-ran,Bian, Hong-tao,Guo, Yuan,et al. Spectroscopic evidence for the specific Na+ and K+ interactions with the hydrogen-bonded water molecules at the electrolyte aqueous solution surfaces[J]. JOURNAL OF CHEMICAL PHYSICS,2009,130(13). |
| APA | Feng, Ran-ran,Bian, Hong-tao,Guo, Yuan,&Wang, Hong-fei.(2009).Spectroscopic evidence for the specific Na+ and K+ interactions with the hydrogen-bonded water molecules at the electrolyte aqueous solution surfaces.JOURNAL OF CHEMICAL PHYSICS,130(13). |
| MLA | Feng, Ran-ran,et al."Spectroscopic evidence for the specific Na+ and K+ interactions with the hydrogen-bonded water molecules at the electrolyte aqueous solution surfaces".JOURNAL OF CHEMICAL PHYSICS 130.13(2009). |
入库方式： OAI收割
来源：化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。