The effects of central metals and peripheral substituents on the photophysical properties and optical limiting performance of phthalocyanines with axial chloride ligand
文献类型：期刊论文
| 作者 | Chen, Jun; Gan, Quan; Li, Shayu; Gong, Fangbin; Wang, Qian; Yang, Zhipei; Wang, Shuangqing; Xu, Huijun; Ma, Jin Shi; Yang, Guoqiang |
| 刊名 | JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY
 |
| 出版日期 | 2009-09-05 |
| 卷号 | 207期号:1页码:58-65 |
| 关键词 | Metal Phthalocyanine Photophysics Optical Limiting Axial Substituent |
| ISSN号 | 1010-6030 |
| DOI | 10.1016/j.jphotochem.2009.04.012 |
| 英文摘要 | A series of peripherally substituted phthalocyanines (Pcs) with different central metals (Al, Ga and In) and axial chloride ligand were synthesized and their photophysical and optical limiting properties were investigated. The Qband absorption of the Pc shifts to longer wavelength with the central metals changing from Al to in, and the fluorescence quantum yields of S(1) emission decrease remarkably from Al to In. Transient absorption spectra of the Pcs in THF were measured in determination of the photophysical parameters. The optical limiting properties were investigated by a nanosecond pulse laser at 532 nm. All of these compounds exhibit good optical limiting performance, and the optical limiting behaviors of solid solution in glass obtained by sol-gel technique are much better than that of liquid solution. Several factors which affect the optical limiting performance of the Pcs with different central metals and substituents are discussed. (C) 2009 Published by Elsevier B.V. |
| 语种 | 英语 |
| WOS记录号 | WOS:000270625100011 |
| 出版者 | ELSEVIER SCIENCE SA |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/66065]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Wang, Shuangqing |
| 作者单位 | Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, CAS Key Lab Photochem, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Chen, Jun,Gan, Quan,Li, Shayu,et al. The effects of central metals and peripheral substituents on the photophysical properties and optical limiting performance of phthalocyanines with axial chloride ligand[J]. JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY,2009,207(1):58-65. |
| APA | Chen, Jun.,Gan, Quan.,Li, Shayu.,Gong, Fangbin.,Wang, Qian.,...&Yang, Guoqiang.(2009).The effects of central metals and peripheral substituents on the photophysical properties and optical limiting performance of phthalocyanines with axial chloride ligand.JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY,207(1),58-65. |
| MLA | Chen, Jun,et al."The effects of central metals and peripheral substituents on the photophysical properties and optical limiting performance of phthalocyanines with axial chloride ligand".JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY 207.1(2009):58-65. |
入库方式： OAI收割
来源：化学研究所
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