Electron structure and substituent effects in o-, m-, p-IC6H4OCH3 iodoanisoles
文献类型：期刊论文
| 作者 | Tong ShengRui; Wang WeiGang; Ma ChunPing; Ge MaoFa; Wang DianXun |
| 刊名 | SCIENCE IN CHINA SERIES B-CHEMISTRY
 |
| 出版日期 | 2009-11-01 |
| 卷号 | 52期号:11页码:1932-1937 |
| 关键词 | Electronic Structures Substituent Effects Ultraviolet Photoelectron Spectroscopy Reactivity |
| ISSN号 | 1006-9291 |
| DOI | 10.1007/s11426-009-0245-2 |
| 英文摘要 | The electronic structures and substituent effects in o-, m-, and p-iodoanisoles have been investigated by ultraviolet photoelectron spectroscopy (UPS). The observed UPS bands were analyzed by combining empirical arguments and theoretical methods. Owing to the electron-donating nature of both iodo- and methoxy substituents, the first ionization potentials of the three iodoanisoles are lower than those of iodobenzene and anisole. The presence of the two substituents in iodoanisoles leads to an electron-rich structure, which might contribute to the observed high reactivity of iodoanisoles in a number of organic reactions. |
| 语种 | 英语 |
| WOS记录号 | WOS:000272032700026 |
| 出版者 | SCIENCE PRESS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/66127]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Ge MaoFa |
| 作者单位 | Chinese Acad Sci, Inst Chem, BNLMS, State Key Lab Struct Chem Unstable & Stable Speci, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Tong ShengRui,Wang WeiGang,Ma ChunPing,et al. Electron structure and substituent effects in o-, m-, p-IC6H4OCH3 iodoanisoles[J]. SCIENCE IN CHINA SERIES B-CHEMISTRY,2009,52(11):1932-1937. |
| APA | Tong ShengRui,Wang WeiGang,Ma ChunPing,Ge MaoFa,&Wang DianXun.(2009).Electron structure and substituent effects in o-, m-, p-IC6H4OCH3 iodoanisoles.SCIENCE IN CHINA SERIES B-CHEMISTRY,52(11),1932-1937. |
| MLA | Tong ShengRui,et al."Electron structure and substituent effects in o-, m-, p-IC6H4OCH3 iodoanisoles".SCIENCE IN CHINA SERIES B-CHEMISTRY 52.11(2009):1932-1937. |
入库方式： OAI收割
来源：化学研究所
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